An article Mesoporous Polymeric Cyanamide-Triazole-Heptazine Photocatalysts for Highly-Efficient Water Splitting WOS:000558656000001 published article about GRAPHITIC CARBON NITRIDE; HYDROGEN EVOLUTION; FACILE SYNTHESIS; SEMICONDUCTORS; REDUCTION; NITROGEN; PERFORMANCE; PRECURSORS; NANOSHEETS; STRATEGY in [Wu, Chongbei; Yu, Guanhang; Yin, Yue; Wang, Yuze; Chen, Li; Han, Qing; Wang, Bo] Beijing Inst Technol, Key Lab Cluster Sci, Key Lab Photoelect Electrophoton Convers Mat, Minist Educ China,Sch Chem & Chem Engn, Beijing 100081, Peoples R China; [Tang, Junwang] UCL, Dept Chem Engn, London WC1E 7JE, England in 2020.0, Cited 65.0. The Name is 1H-1,2,4-Triazol-5-amine. Through research, I have a further understanding and discovery of 61-82-5. COA of Formula: C2H4N4
Conjugated polymers are promising light harvesters for water reduction/oxidation due to their simple synthesis and adjustable bandgap. Herein, both cyanamide and triazole functional groups are first incorporated into a heptazine-based carbon nitride (CN) polymer, resulting in a mesoporous conjugated cyanamide-triazole-heptazine polymer (CTHP) with different compositions by increasing the quantity of cyanamide/triazole units in the CN backbone. Varying the compositions of CTHP modulates its electronic structures, mesoporous morphologies, and redox energies, resulting in a significantly improved photocatalytic performance for both H(2)and O(2)evolution under visible light irradiation. A remarkable H(2)evolution rate of 12723 mu mol h(-1)g(-1)is observed, resulting in a high apparent quantum yield of 11.97% at 400 nm. In parallel, the optimized photocatalyst also exhibits an O(2)evolution rate of 221 mu mol h(-1) g(-1), 9.6 times higher than the CN counterpart, with the value being the highest among the reported CN-based bifunctional photocatalysts. This work provides an efficient molecular engineering approach for the rational design of functional polymeric photocatalysts.
About 1H-1,2,4-Triazol-5-amine, If you have any questions, you can contact Wu, CB; Yu, GH; Yin, Y; Wang, YZ; Chen, L; Han, Q; Tang, JW; Wang, B or concate me.. COA of Formula: C2H4N4
Reference:
Article; Safari, Niloufar; Shirini, Farhad; Tajik, Hassan; Journal of Molecular Structure; vol. 1201; (2020);,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics