Day: December 30, 2022

Utilization of cationic microporous metal-organic framework for efficient Xe/Kr separation was written by Gong, Lingshan;Liu, Ying;Ren, Junyu;Al-Enizi, Abdullah M.;Nafady, Ayman;Ye, Yingxiang;Bao, Zongbi;Ma, Shengqian. And the article was included in Nano Research in 2022.Name: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid This article mentions the following:

The separation of xenon/krypton (Xe/Kr) mixtures plays a vital role in the industrial process of manufacturing high-purity xenon. Compared with energy-intensive cryogenic distillation, porous materials based on phys. adsorption are very promising in the low-cost and energy-saving separation processes. Herein, we show that a cationic metal-organic framework (named as FJU-55) exhibits highly efficient Xe/Kr separation performance, which can be attributable to its uniform three-dimensional (3D) interconnection channels and the electro-pos. features as the host framework. Moreover, FJU-55 demonstrates good Xe adsorption capacity of 1.41 mmol/g and excellent Xe/Kr selectivity of 10 (298 K and 100 kPa), together with a high Qst value of 39.4 kJ/mol at low coverage area. The superior Xe/Kr separation performance of FJU-55 was further confirmed by the dynamic breakthrough experiments Results obtained via mol. modeling studies have revealed that the suitable pore size and abundant accessible aromatic ligands in FJU-55 could offer strong multiple C-H^..Xe interactions, which play a collaborative role in this challenging gas separation task. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Name: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Triazoles are important five-member nitrogen heterocycles involved in a wide range of industrial applications such as agrochemicals, corrosion inhibitors, dyes, optical brighteners, as well as biologically active agents. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Name: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

A series of Zn(II) and Cd(II) coordination compounds based on 4-(4H-1,2,4-triazol-4-yl)benzoic acid: synthesis, structure and photoluminescence properties was written by Yang, Li-Bo;Wang, Hong-Can;Fang, Xiao-Dan;Chen, Si-Jin;Xu, Quan-Qing;Zhu, Ai-Xin;Yang, Zhi. And the article was included in CrystEngComm in 2016.Product Details of 157069-48-2 This article mentions the following:

Seven coordination compounds, namely [Zn(4-tba)₂(H₂O)₂] (1), [Zn(4-tba)Cl]·CH₃OH (2), [Zn(4-tba)₂] (3), [Zn(4-tba)₂]·DMA·3.5H₂O (4), [Cd(4-tba)₂]·DMF·3.6H₂O (5), [Cd(4-tba)₂] (6) and [Cd₅Cl₄(4-tba)₆]·1.5DMF·4H₂O (7) (4-Htba = 4-(4H-1,2,4-triazol-4-yl)benzoic acid, DMA = N,N-dimethylacetamide and DMF = N,N-dimethylformamide), have been synthesized under hydro/solvothermal conditions by using a triazolate-carboxylate bifunctional organic ligand, 4-Htba. Complexes 1 and 2 exhibit a mononuclear motif and a two-dimensional (2D) network with sql topol., resp., whereas 3-6 display different interpenetrating structures. Compound 3 shows a 2-fold interpenetrating 2D net with sql topol., 4 and 5 display uninodal 4-connected 4-fold interpenetrating 3D nets with dia (6⁶) topol. belonging to class Ia and class IIIa, resp., and compound 6 exhibits a 5-fold interpenetrating dia net. Complex 7 exhibits a non-interpenetrating 3D framework constructed from decanuclear cadmium-chloride chain units and 4-tba ligands with various coordination modes. All the complexes were characterized using single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), IR spectroscopy and elemental analyses. In addition, the thermogravimetric anal. and solid-state photoluminescence results for 1–7 were also investigated. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Product Details of 157069-48-2).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. Triazole growth retardants such as uniconazole and paclobutrazol have been known to inhibit the biosynthesis of gibberellins by blocking kaurene oxidase, an P450 enzymeProduct Details of 157069-48-2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Two mechanisms provide tolerance to cyhalofop-butyl in pond lovegrass [Eragrostis japonica (Thunb.) Trin.] was written by Liu, Ying;Wang, Hao;Gao, Haitao;Zhu, Guangtao;Peng, Zhen;Li, Jun;Dong, Liyao. And the article was included in Pesticide Biochemistry and Physiology in 2022.Electric Literature of C6H6N4 This article mentions the following:

Pond lovegrass [Eragrostis japonica (Thunb.) Trin.] is an annual grass weed of rice fields worldwide. Cyhalofop-Bu has been widely used for controlling annual grass weeds in rice fields. However, E. japonica is tolerant to cyhalofop-Bu. The ED values of cyhalofop-Bu for 29 E. japonica populations causing 50% inhibition of fresh weight (GR50: 130.15 to 187.61 g a.i. ha^-1) were much higher than the recommended dose of cyhalofop-Bu (75 g a.i. ha^-1) in the field. The mechanisms of tolerance to cyhalofop-Bu in E. japonica were identified. In vitro activity assays revealed that the cyhalofop-Bu concentration required to inhibit 50% of the acetyl-CoA carboxylase (ACCase) activity (IC₅₀) was 6.22-fold higher in E. japonica than that in the cyhalofop-butyl-susceptible Chinese sprangletop [Leptochloa chinensis (L.) Nees]. However, mutations in the ACCase gene, previously found to endow target-site resistance in weeds, were not detected in the sequences obtained. Addnl., the expression level of genes encoding ACCase in E. japonica was found to be as similar to L. chinensis. Tolerance was reduced by two cytochrome P 450 monooxygenases (Cyt P450s) inhibitors (1-aminobenzotriazole and piperonyl butoxide) and the activity of NADPH-dependent cytochrome P 450 reductase in E. japonica was approx. 4.46-fold higher than that of L. chinensis after cyhalofop-Bu treatment. Taken together, it is concluded that two co-existing mechanisms, an insensitive target ACCase and an enhanced metabolism mediated by Cyt P450s, endow tolerance to cyhalofop-Bu in E. japonica. In the experiment, the researchers used many compounds, for example, 1H-Benzo[d][1,2,3]triazol-1-amine (cas: 1614-12-6Electric Literature of C6H6N4).

1H-Benzo[d][1,2,3]triazol-1-amine (cas: 1614-12-6) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Triazole growth retardants such as uniconazole and paclobutrazol have been known to inhibit the biosynthesis of gibberellins by blocking kaurene oxidase, an P450 enzymeElectric Literature of C6H6N4

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN¹]manganese(II) decahydrate was written by Piao, Ying Ai;Xuan, Zhen Yu. And the article was included in Acta Crystallographica, Section E: Structure Reports Online in 2011.Formula: C9H7N3O2 This article mentions the following:

In the title compound, [Mn(C₉H₆N₃O₂)₂(H₂O)₄]·10H₂O, the Mn^II ion is coordinated by two N atoms from two 4-(4H-1,2,4-triazol-4-yl)benzoate ligands and four water mols. in a distorted octahedral geometry. The Mn^II ion and two coordinated water mols. lie on a twofold rotation axis. The water mols. are involved in O-H···N and O-H···O hydrogen bonds with the triazole N atoms and carboxylate O atoms, yielding a three-dimensional supramol. network. π-π Interactions between the benzene rings [centroid-centroid distance = 3.836(9) Å] are observed In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Formula: C9H7N3O2).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Both the triazoles and their derivatives have significant biological properties including antimicrobial, antiviral, antitubercular, anticancer, anticonvulsant, analgesic, antioxidant, anti-inflammatory, and antidepressant activities.Formula: C9H7N3O2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Diaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κ²O,O’]cobalt(II), and the cadmium(II) and copper(II) analogues: new self-complementary hydrogen-bond donor/acceptor modules for designing hydrogen-bonded frameworks was written by Lukashuk, Liliana V.;Lysenko, Andrey B.;Rusanov, Eduard B.;Chernega, Alexander N.;Domasevitch, Konstantin V.. And the article was included in Acta Crystallographica, Section C: Crystal Structure Communications in 2007.Category: triazoles This article mentions the following:

In the isostructural title complexes, [M(C₉H₆N₃O₂)₂(H₂O)₂] [M = Co^II, (I), Cd^II, (II), and Cu^II, (III); the metal centers reside on a twofold axis in the space group C2/c for (I) and (II)], the metal centers are surrounded by four O atoms from two O,O’-bidentate carboxylate groups and by two trans-coordinated aqua ligands, forming a distorted octahedral environment. The mols. possess four hydrogen-bond donor (two aqua ligands) and four hydrogen-bond acceptor sites (two triazole groups), and aggregate by self-association, forming two-dimensional hydrogen-bonded frameworks [via O-H…N interactions; O…N = 2.749(3)-2.872(3) Å]. The layers are parallel and are tightly packed with short interlayer distances of 4.93, 4.95, and 5.01 Å for (I), (II), and (III), resp. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Category: triazoles).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. Both the triazoles and their derivatives have significant biological properties including antimicrobial, antiviral, antitubercular, anticancer, anticonvulsant, analgesic, antioxidant, anti-inflammatory, and antidepressant activities.Category: triazoles

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Cobalt(II)-Lanthanide(III) Heterometallic Metal-Organic Frameworks with Unique (6,6)-Connected Nia Topologies with 1H-1,2,3-Triazole-4,5-dicarboxylic Acid: Syntheses, Structures and Magnetic Properties was written by Zou, Ji-Yong;Shi, Wei;Xu, Na;Gao, Hong-Ling;Cui, Jian-Zhong;Cheng, Peng. And the article was included in European Journal of Inorganic Chemistry in 2014.Application of 4546-95-6 This article mentions the following:

Four isostructural cobalt(II)-lanthanide(III) heterometallic metal-organic frameworks (MOFs), formulated as {[(CH₃)₂NH₂]₃[Co₃Ln(tda)₃(HCOO)₃]·2H₂O·0.75DMF}_n [Ln = Eu (Co-Eu), Gd (Co-Gd), Tb (Co-Tb), and Dy (Co-Dy); H₃tda = 1H-1,2,3-triazole-4,5-dicarboxylic acid] were successfully synthesized and structurally characterized. In these Co-Ln heterometallic MOFs, three neighboring Co^II ions are connected by HCOO^– anions to form triangular [Co₃(HCO₂)₃]³⁺ clusters. The equivalent triangular [Co₃(HCO₂)₃]³⁺ clusters are connected by six tda^3- anions to generate a 1D trigonal prismatic chain, which are further interconnected through Ln^III ions to give unique 3D (6,6)-connected nia nets with the Schlaefli symbol of (4¹² 6³) (4⁹ 6⁶). The magnetic properties of the four isostructural Co-Ln heterometallic MOFs also were studied. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Application of 4546-95-6).

1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. Triazoles exhibit substantial isomerism, depending on the positioning of the nitrogen atoms within the ring. Due to the structural characteristics, both 1,2,3- and 1,2,4-triazoles are able to accommodate a broad range of substituents (electrophiles and nucleophiles) around the core structures and pave the way for the construction of diverse novel bioactive molecules.Application of 4546-95-6

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Synthesis and Reactivity of Rhodium(II) N-Triflyl Azavinyl Carbenes was written by Grimster, Neil;Zhang, Li;Fokin, Valery V.. And the article was included in Journal of the American Chemical Society in 2010.Electric Literature of C5H7N3O2 This article mentions the following:

Highly reactive rhodium(II) N-trifluoromethylsulfonyl azavinyl carbenes are formed in situ from NH-1,2,3-triazoles, triflic anhydride, and rhodium carboxylates. They rapidly and selectively react with olefins, providing cyclopropane carboxaldehydes and 2,3-dihydropyrroles in generally excellent yields and high enantio- and diastereoselectivity. In the experiment, the researchers used many compounds, for example, Ethyl 1H-1,2,3-triazole-5-carboxylate (cas: 40594-98-7Electric Literature of C5H7N3O2).

Ethyl 1H-1,2,3-triazole-5-carboxylate (cas: 40594-98-7) belongs to triazole derivatives. Among the nitrogen-containing heterocyclic compounds, triazoles emerge with superior pharmacological applications. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Electric Literature of C5H7N3O2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Proteomic analysis of liver proteins of mice exposed to 1,2-dichloropropane was written by Zhang, Xiao;Morikawa, Kota;Mori, Yurie;Zong, Cai;Zhang, Lingyi;Garner, Edwin;Huang, Chinyen;Wu, Wenting;Chang, Jie;Nagashima, Daichi;Sakurai, Toshihiro;Ichihara, Sahoko;Oikawa, Shinji;Ichihara, Gaku. And the article was included in Archives of Toxicology in 2020.Product Details of 1614-12-6 This article mentions the following:

The aim of the present study was to characterize the mol. mechanisms of 1,2-DCP-induced hepatotoxic effects by proteomic anal. We analyzed quant. the differential expression of proteins in the mouse liver and investigated the role of P 450 in mediating the effects of 1,2-DCP. Male C57BL/6JJcl mice were exposed to 0, 50, 250, or 1250 ppm 1,2-DCP and treated with either 1-aminobenzotriazole (1-ABT), a nonselective P 450 inhibitor, or saline, for 8 h/day for 4 wk. Two-dimensional difference in gel electrophoresis (2D-DIGE) combined with matrix-assisted laser-desorption ionization time-of-flight mass spectrometry (MALDI-TOF/TOF/MS) was used to detect and identify proteins affected by the treatment. PANTHER overrepresentation test on the identified proteins was conducted. 2D-DIGE detected 61 spots with significantly different intensity between 0 and 250 ppm 1,2-DCP groups. Linear regression anal. showed significant trend with 1,2-DCP level in 17 proteins in mice co-treated with 1-ABT. 1-ABT mitigated the differential expression of these proteins. The gene ontol. enrichment anal. showed overrepresentation of proteins functionally related to nickel cation binding, carboxylic ester hydrolase activity, and catalytic activity. The results demonstrated that exposure to 1,2-DCP altered the expression of proteins related with catalytic and carboxylic ester hydrolase activities, and that such effect was mediated by P 450 enzymic activity. In the experiment, the researchers used many compounds, for example, 1H-Benzo[d][1,2,3]triazol-1-amine (cas: 1614-12-6Product Details of 1614-12-6).

1H-Benzo[d][1,2,3]triazol-1-amine (cas: 1614-12-6) belongs to triazole derivatives. Triazoles exhibit substantial isomerism, depending on the positioning of the nitrogen atoms within the ring. Triazoles are compounds with a vast spectrum of applications, varying from materials (polymers), agricultural chemicals, pharmaceuticals, photoactive chemicals and dyes.Product Details of 1614-12-6

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

A new family of 3d-4f heterometallic coordination polymers assembled with 1H-1,2,3-triazole-4,5-dicarboxylic acid: syntheses, structures and magnetic properties was written by Zou, Ji-Yong;Xu, Na;Shi, Wei;Gao, Hong-Ling;Cui, Jian-Zhong;Cheng, Peng. And the article was included in RSC Advances in 2013.Synthetic Route of C4H3N3O4 This article mentions the following:

Five isostructural copper(II)-lanthanide(iii) heterometallic coordination polymers (CPs), {[Cu₂Ln(TDA)₂Cl(H₂O)₄]·2H₂O}_n [Ln = Gd (Cu-Gd), Tb (Cu-Tb), Dy (Cu-Dy), Ho (Cu-Ho) and Er (Cu-Er)] (H₃TDA = 1H-1,2,3-triazole-4,5-dicarboxylic acid), were synthesized under solvothermal conditions and structurally characterized. In these CPs, two neighboring Cu(II) ions are connected via one μ₂-Cl to form [Cu₂Cl]³⁺ units, which are further linked into a copper chain through bridging TDA^3-. The neighboring copper chains are further connected by lanthanide to form a two-dimensional structure with sql topol. The magnetic properties of the five isostructural heterometallic CPs were studied as well. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Synthetic Route of C4H3N3O4).

1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Synthetic Route of C4H3N3O4

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Lanthanide-based coordination compounds based on 4-(4-carboxyphenyl)-1,2,4-triazole: synthesis, structures, Hirshfeld surface and luminescence properties was written by Liu, Qing-Ling;Yang, Li-Jing;Luo, Yang-Hui;Sun, Bai-Wang. And the article was included in New Journal of Chemistry in 2016.Synthetic Route of C9H7N3O2 This article mentions the following:

Four novel lanthanide compounds based on the 4-(4-carboxyphenyl)-1,2,4-triazole ligand (Hcpt), {[Pr₂(cpt)₄(H₂O)₁₀]·10H₂O·2ClO₄} (1), {[Ln(cpt)₂(H₂O)₂(OH)]·4H₂O}_n (Ln = Er (2), Lu (3)), and {[Sm(cpt)₂(CH₃CH₂OH)(H₂O)₃]·ClO₄}_n (4), were obtained under hydrothermal conditions and further characterized by elemental anal., single-crystal x-ray diffraction and TGA. Compound 1 exhibits a discrete dinuclear structure constructed by one cpt^– ligand coordinated to two Pr³⁺ ions and another cpt^– ligand coordinated to more than one Pr³⁺ ion. Compounds 2 and 3 are isomorphous and every cpt^– ligand coordinates to two Ln³⁺ ions, resulting in a polymeric 1-dimensional chain structure. Different from the above compounds, the nitrogen atoms of triazole are also involved in the coordination of compound 4. One cpt^– ligand coordinates to two Sm³⁺ ions and another cpt^– ligand coordinates to more than one Sm³⁺ ion, meanwhile, the nitrogen atoms of triazole coordinate to the 3rd Sm³⁺ ion, resulting in a 2-dimensional polymeric network structure. The luminescence properties of compound 4 were characterized, and it exhibited characteristic Sm³⁺ emission in the yellow region. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Synthetic Route of C9H7N3O2).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Triazoles consist of a five-membered ring containing three nitrogen atoms and are biologically active, especially as antifungal, antimicrobial and enzyme inhibitors. The presence of the three nitrogen atoms in triazole structures afforded opportunities for a plethora of structural modification with the generation of novel therapeutically potential agents, which is different from other heterocyclic compounds.Synthetic Route of C9H7N3O2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics