Day: February 13, 2023

4,5-Dicyano-1,2,3-Triazole-A Promising Precursor for a New Family of Energetic Compounds and Its Nitrogen-Rich Derivatives: Synthesis and Crystal Structures was written by Cao, Wenli;Qin, Jian;Zhang, Jianguo;Sinditskii, Valery P.. And the article was included in Molecules in 2021.Application of 4546-95-6 This article mentions the following:

The nitrogen-rich compounds and intermediates with structure of monocyclic, bicyclic, and fused rings based on 1,2,3-triazole were synthesized and prepared by using a promising precursor named 4,5-dicyano-1,2,3-triazole, which was obtained by the cyclization reaction of diaminomaleonitrile. Their structure and configurational integrity were assessed by Fourier transform-IR spectroscopy (FT-IR), mass spectrometry (MS), and elemental anal. (EA). Addnl., fourteen compounds were further confirmed by X-ray single crystal diffraction. Meanwhile, the phys. properties of four selected compounds including thermal stability, detonation parameters, and sensitivity were also estimated All these compounds could be considered to construct more abundant 1,2,3-triazole-based neutral energetic mols., salts, and complex compounds, which need to continue study in the future in the field of energetic materials. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Application of 4546-95-6).

1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. Among the nitrogen-containing heterocyclic compounds, triazoles emerge with superior pharmacological applications. Triazole growth retardants such as uniconazole and paclobutrazol have been known to inhibit the biosynthesis of gibberellins by blocking kaurene oxidase, an P450 enzymeApplication of 4546-95-6

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Two threefold Interpenetrating 3D Supramolecular Networks Based on 1D Chains and Hydrogen-bond Interactions was written by Zhu, Ai-Xin;Yang, Li-Bo;Fang, Xiao-Dan;Zhang, Ce;Dou, Ai-Na;Yin, Qi. And the article was included in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2017.Synthetic Route of C9H7N3O2 This article mentions the following:

The coordination compounds, [Cu₂(Htba)(tba)Cl] (1) and [Ag₂(Htba)(tba)(NO₃)] (2), were synthesized under solvothermal conditions by using a triazolate-carboxylate bifunctional organic ligand 4-(4H-1,2,4-triazol-4-yl)benzoic acid (Htba). X-ray single crystal diffraction analyses for the two complexes revealed that compounds 1 and 2 exhibit one-dimensional (1D) chain structures with uncoordinated carboxylic groups, which are further connected by O-H璺矾璺疧 hydrogen bonds into 3D, threefold interpenetrating supramol. frameworks with different topologies belonging to 4-connected and (2,4)-connected nets with the (4²璺?²璺?0²)(4³璺?²璺?)₂(4⁴璺?²) and (12⁵璺?6)(12)₂ Schlaefli symbols, resp. The photoluminescent measurements reveal that both 1 and 2 exhibit bluish-purple emissions in the solid state at room temperature In addition, the compound 2 can serve as an antenna for sensitizing the visible-emitting of the lanthanide cations to display their characteristic emissions. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Synthetic Route of C9H7N3O2).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Synthetic Route of C9H7N3O2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

The ir and uv spectra, and reactivity with inorganic ions, of 1,2,3-triazole-4,5-dicarboxylic acid was written by Capitan, F.;Salinas, F.;Alonso, E. J.. And the article was included in Anales de Quimica (1968-1979) in 1973.Application of 4546-95-6 This article mentions the following:

1,2,3-triazole-4,5-dicarboxylic acid was prepared according to the literature, and its ir and uv spectra was established. The acidity constants were determined from the influence of the pH on the uv spectrum. The reactivity against 45 inorganic ions was studied also. This substance possesses a high selective character, because it only reacts with the cations Ag(I), Pb(II), Hg2(II), Hg(II), Cu(II), Pd(II), Co(II), Cr(III), and Rh(III). The sensitivities of these reactions are low. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Application of 4546-95-6).

1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. However, triazoles are also useful in bioorthogonal chemistry, because the large number of nitrogen atoms causes triazoles to react similar to azides. Due to the structural characteristics, both 1,2,3- and 1,2,4-triazoles are able to accommodate a broad range of substituents (electrophiles and nucleophiles) around the core structures and pave the way for the construction of diverse novel bioactive molecules.Application of 4546-95-6

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics