Research speed reading in 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. 1455-77-2, name is 3,5-Diamino-1,2,4-triazole belongs to triazoles compound, it is a common compound, a new synthetic route is introduced below. Computed Properties of C2H5N5
A mixture of Hdatrz (19.8mg, 0.2mmol), CH3-H2ip (36.0mg, 0.2mmol) and Co(OAc)2·4H2O (24.9mg, 0.1mmol) was dissolved in mixed H2O?CH3OH (v:v=1:1, 10.0mL) solution, and the initial pH value of the reactant mixture was adjusted to ca. 6 by slow addition of triethylamine with constant stirring. The resulting mixture was then transferred into a Teflon-lined stainless steel vessel (23.0mL) and heated at 160°C for 96h under autogenous pressure. After the mixture was cooled to room temperature at a rate of 1.4°Ch?1, red block-shaped crystals suitable for X-ray analysis were obtained directly, washed with water and dried in air (Yield: 50percent, based on CoII salt). Anal. Calc. for C12H15CoN5O5: C, 39.14; H, 4.11; N, 19.02. Found: C, 39.14; H, 4.12; N, 19.05percent. IR (KBr pellet, cm?1): 3445 (s), 3333 (w), 3070 (w), 1670 (s), 1633 (s), 1546 (s), 1439 (s), 1370 (s), 1246 (w), 1083 (m), 1032 (m), 817 (w), 783 (m), 751 (w), 723 (m).
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3,5-Diamino-1,2,4-triazole, in my other articles.
Reference:
Article; Zhao, Hong; Li, Hong-Xue; Liu, Zhong-Yi; Yang, En-Cui; Zhao, Xiao-Jun; Polyhedron; vol. 101; (2015); p. 29 – 36;,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics