A series of Zn(II) and Cd(II) coordination compounds based on 4-(4H-1,2,4-triazol-4-yl)benzoic acid: synthesis, structure and photoluminescence properties was written by Yang, Li-Bo;Wang, Hong-Can;Fang, Xiao-Dan;Chen, Si-Jin;Xu, Quan-Qing;Zhu, Ai-Xin;Yang, Zhi. And the article was included in CrystEngComm in 2016.Product Details of 157069-48-2 This article mentions the following:
Seven coordination compounds, namely [Zn(4-tba)2(H2O)2] (1), [Zn(4-tba)Cl]·CH3OH (2), [Zn(4-tba)2] (3), [Zn(4-tba)2]·DMA·3.5H2O (4), [Cd(4-tba)2]·DMF·3.6H2O (5), [Cd(4-tba)2] (6) and [Cd5Cl4(4-tba)6]·1.5DMF·4H2O (7) (4-Htba = 4-(4H-1,2,4-triazol-4-yl)benzoic acid, DMA = N,N-dimethylacetamide and DMF = N,N-dimethylformamide), have been synthesized under hydro/solvothermal conditions by using a triazolate-carboxylate bifunctional organic ligand, 4-Htba. Complexes 1 and 2 exhibit a mononuclear motif and a two-dimensional (2D) network with sql topol., resp., whereas 3-6 display different interpenetrating structures. Compound 3 shows a 2-fold interpenetrating 2D net with sql topol., 4 and 5 display uninodal 4-connected 4-fold interpenetrating 3D nets with dia (66) topol. belonging to class Ia and class IIIa, resp., and compound 6 exhibits a 5-fold interpenetrating dia net. Complex 7 exhibits a non-interpenetrating 3D framework constructed from decanuclear cadmium-chloride chain units and 4-tba ligands with various coordination modes. All the complexes were characterized using single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), IR spectroscopy and elemental analyses. In addition, the thermogravimetric anal. and solid-state photoluminescence results for 1–7 were also investigated. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Product Details of 157069-48-2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. Triazole growth retardants such as uniconazole and paclobutrazol have been known to inhibit the biosynthesis of gibberellins by blocking kaurene oxidase, an P450 enzymeProduct Details of 157069-48-2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics