Synthesis and characterization of a novel one-dimensional Zn(II) coordination polymer based on in situ generated 1-methyl-2-(3H-[1,2,3]triazol-4-yl)-1H-benzoimidazole was written by Sun, Chen-guang;Xu, Kang-zhen;Yin, Zheng;Song, Ji-rong;Zeng, Ming-hua. And the article was included in Inorganic Chemistry Communications in 2012.Application of 4546-95-6 This article mentions the following:
One novel 1-dimensional chain of {[Zn2(L)3(H2O)(NO3)]·2.5H2O}n (1)(HL = 1-methyl-2-(3H-[1,2,3]triazol-4-yl)-1H-benzoimidazole) was hydrothermally constructed from in situ generated 1-methyl-2-(3H-[1,2,3]triazol-4-yl)-1H-benzoimidazole ligand at 160°. Compound 1 exhibits a 1-dimensional butterfly-like chain architecture, which is further assembled into a 3-dimensional supermol. network by interchain H bonds. TGA studies show that compound 1 is highly thermally stable. The fluorescent property in the solid state is also explored, and the emission spectrum shows a blue shift of 62 nm compared with that of HL, which may be assigned to ligand-to-metal charge transfer. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Application of 4546-95-6).
1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. 1,2,3-Triazoles are usually prepared following (3+2) cycloaddition protocols. A common technique for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However, the Huisgen strategy produces a mixture of isomers (typically 1,4- and 1,5-disubstituted) when used to produce substituted triazoles.Application of 4546-95-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics