A high-activity cobalt-based MOF catalyst for [2 + 2 + 2] cycloaddition of diynes and alkynes: insights into alkyne affinity and selectivity control was written by Xu, Fen;Si, Xiao-Ju;Wang, Xiao-Ning;Kou, Hao-Dong;Chen, Di-Ming;Liu, Chun-Sen;Du, Miao. And the article was included in RSC Advances in 2018.Computed Properties of C9H7N3O2 This article mentions the following:
This work developed a highly efficient metal-organic framework (MOF) catalyst for the straightforward synthesis of functionalized benzenes via [2 + 2 + 2] cycloaddition As efficient cooperative catalyst for such reactions, Co-MOF-1, showed great sustainability and efficiency. This new catalytic system led to the generation of a series of structurally diverse benzenes in good to excellent yields (up to 95%). In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Computed Properties of C9H7N3O2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Computed Properties of C9H7N3O2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics