Field-induced single-ion magnet behavior in a hydrogen-bonded supramolecular cobalt(II) complex was written by Shao, Dong;She, Shi-Yuan;Shen, Lin-Feng;Yang, Xiaodong;Tian, Zhengfang. And the article was included in Polyhedron in 2022.Computed Properties of C9H7N3O2 This article mentions the following:
Hydrogen-bonded supramol. frameworks remain highly interesting for the development of novel porous materials. Herein a hydrogen-bonded supramol. framework of a cobalt(II) complex, [Co(cpt)2(H2O)2] (Hcpt = 4-(p-carboxyphenyl)-1,2,4-triazole), was synthesized and structurally characterized. A single crystal X-ray diffraction (SC-XRD) study indicates that the monometallic Co2+ ion is located in a distorted octahedral geometry and the complex forms a two-dimensional supramol. network stabilized by significant intermol. N···H interactions. Variable-temperature PXRD and TGA anal. experiments revealed considerable thermal stability of the supramol. framework of the CoII complex. Magnetic studies showed that the distorted octahedral Co2+ ion exhibits considerable easy-plane magnetic anisotropy with D = 22.3 cm-1, while field-induced single-ion magnet (SIM) behavior was evidenced at low temperature The forgoing results further highlight that the hydrogen-bonded supramol. framework could be used as a great platform for the development of mol. nanomagnets. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Computed Properties of C9H7N3O2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. However, triazoles are also useful in bioorthogonal chemistry, because the large number of nitrogen atoms causes triazoles to react similar to azides. The presence of the three nitrogen atoms in triazole structures afforded opportunities for a plethora of structural modification with the generation of novel therapeutically potential agents, which is different from other heterocyclic compounds.Computed Properties of C9H7N3O2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics