Recently I am researching about METAL-ORGANIC FRAMEWORKS; THERMAL-DECOMPOSITION; GRAPHITE; RDX; EXPLOSIVES; COMPLEXES; BEHAVIOR, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21703002, 21727805, 21673180]; Natural Science Basic Research Plan in Shaanxi Province of China [2019JQ-180]; Shaanxi Provincial Key Laboratory Project [13JS006]; Doctoral Scientific Research Starting Foundation of Baoji University of Arts and Science [ZK2017024]; Open Foundation of Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of Ministry of Education [338050067(2018-008)]; Graduate Student Innovation Fund of Baoji University of Arts And Sciences [YJSCX19YB02]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Yang, DS; Mo, WJ; Zhang, S; Li, B; Hu, DW; Chen, SP. The CAS is 61-82-5. Through research, I have a further understanding and discovery of 1H-1,2,4-Triazol-5-amine. SDS of cas: 61-82-5
A new energetic coordination polymer (ECP) composite, namely GO-Cu(II)-AmTZ, has been synthesized by 3-amino-1,2,4-triazole (AmTZ) and multifunctional graphene oxide (GO) coordination with Cu(II) successively. The ECP composite was further characterized through SEM, EDS and XPS analysis as well as FTIR and Raman spectroscopy. It shows high thermostability, high decomposition heat release and insensitivity to mechanical stimuli. What’s more, thermal analysis data for ammonium perchlorate (AP) have been obtained by mechanically mixing GO-Cu(II)-AmTZ and AP. The low-temperature decomposition (LTD, 335.3 degrees C) and high-temperature decomposition (HTD, 441.3 degrees C) peaks of AP were reduced to an exothermic peak at 298.4 degrees C at a heating rate of 10 degrees C min(-1). GO-Cu(II)-AmTZ exhibits outstanding catalytic performance by decreasing the activation energy from 168.7 kJ mol(-1) to 122.4 kJ mol(-1), indicating its promising application as a combustion catalyst for improving the thermal-catalytic decomposition performance of energetic materials largely. In addition, thermal analysis techniques including thermogravimetry coupled with mass spectrometry (TG/MS) and thermogravimetry coupled with infrared spectrometry (TG/IR) were employed to determine the decomposition mechanisms.
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Reference:
Article; Safari, Niloufar; Shirini, Farhad; Tajik, Hassan; Journal of Molecular Structure; vol. 1201; (2020);,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics