In 2017,Gross, Andrew J.; Chen, Xiaohong; Giroud, Fabien; Travelet, Christophe; Borsali, Redouane; Cosnier, Serge published 《Redox-active glyconanoparticles as electron shuttles for mediated electron transfer with bilirubin oxidase in solution》.Journal of the American Chemical Society published the findings.SDS of cas: 56602-33-6 The information in the text is summarized as follows:
We demonstrate the self-assembly, characterization, and bioelectrocatalysis of redox-active cyclodextrin-coated nanoparticles. The nanoparticles with host-guest functionality are easy to assemble and permit entrapment of hydrophobic redox mols. in aqueous solution Bis-pyrene-ABTS encapsulated nanoparticles were investigated electrochem. and spectroscopically. Their use as electron shuttles was demonstrated via an intra-electron transfer chain between neighboring redox units of clustered particles (Dh,DLS = 195 nm) and the mono- and trinuclear Cu sites of bilirubin oxidases. Enhanced current densities for mediated O2 reduction were observed with the redox nanoparticle system compared to equivalent bioelectrode cells with a dissolved mediator. Improved catalytic stability over 2 days was also observed with the redox nanoparticles, highlighting a stabilizing effect of the polymeric architecture. Bioinspired nanoparticles as mediators for bioelectrocatalysis promises to be valuable for future biofuel cells and biosensors. In the experiment, the researchers used ((1H-Benzo[d][1,2,3]triazol-1-yl)oxy)tris(dimethylamino)phosphonium hexafluorophosphate(V)(cas: 56602-33-6SDS of cas: 56602-33-6)
((1H-Benzo[d][1,2,3]triazol-1-yl)oxy)tris(dimethylamino)phosphonium hexafluorophosphate(V)(cas: 56602-33-6) is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.SDS of cas: 56602-33-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics