《Chemically Triggered Synthesis, Remodeling, and Degradation of Soft Materials》 was published in Journal of the American Chemical Society in 2020. These research results belong to Sun, Xiaolong; Chwatko, Malgorzata; Lee, Doo-Hee; Bachman, James L.; Reuther, James F.; Lynd, Nathaniel A.; Anslyn, Eric V.. Application of 510758-28-8 The article mentions the following:
Polymer topol. dictates dynamic and mech. properties of materials. For most polymers, topol. is a static characteristic. In this article, we present a strategy to chem. trigger dynamic topol. changes in polymers in response to a specific chem. stimulus. Starting with a dimerized PEG and hydrophobic linear materials, a lightly crosslinked polymer, and a crosslinked hydrogel, transformations into an amphiphilic linear polymer, lightly crosslinked and linear random copolymers, a crosslinked polymer, and three different hydrogel matrixes were achieved via two controllable crosslinking reactions: reversible conjugate additions and thiol-disulfide exchange. Significantly, all the polymers, before or after topol. changes, can be triggered to degrade into thiol- or amine-terminated small mols. The controllable transformations of polymeric morphologies and their degradation herald a new generation of smart materials. The experimental part of the paper was very detailed, including the reaction process of Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8Application of 510758-28-8)
Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8) can stabilizes Cu(I) towards disproportionation and oxidation thus enhancing its catalytic effect in the azide-acetylene cycloaddition.Application of 510758-28-8Polytriazolylamines were synthesized by the copper(I)-catalyzed ligation of azides and alkynes.
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics