《Direct synthesis of well-defined zwitterionic cyclodextrin polymers via atom transfer radical polymerization》 was written by Diget, Jakob Stensgaard; Stade, Lars Wagner; Nielsen, Thorbjoern Terndrup. Recommanded Product: Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amineThis research focused onzwitterionic cyclodextrin polymer atom transfer radical polymerization. The article conveys some information:
A versatile atom transfer radical polymerization (ATRP) protocol was developed for the direct homo- and copolymerization of a sulfobetaine monomer, [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium (SBMA), and a mono-functionalized β-cyclodextrin (βCD) methacrylate monomer. The polymers were characterized using 1- and 2D NMR spectroscopy and asym. flow field-flow fractionation (AF4). Low dispersities (DM = Mw/Mn) and high initiator efficiencies, of both the homo- and copolymers, indicated good control of the polymerization The work thus represents one of the few reports where low DM values are obtained for direct ATRP of SBMA and βCD monomers. The novel βCD copolymer showed salt-dependent upper critical solution temperature (UCST) behavior, while isothermal titration calorimetry revealed excellent binding properties. In the experiment, the researchers used many compounds, for example, Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8Recommanded Product: Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine)
Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8) is a polytriazolylamine ligand which stabilizes Cu(I) towards disproportionation and oxidation thus enhancing its catalytic effect in the azide-acetylene cycloaddition.Recommanded Product: Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics