Watt, Fabian A.; Sieland, Benedikt; Dickmann, Nicole; Schoch, Roland; Herbst-Irmer, Regine; Ott, Holger; Paradies, Jan; Kuckling, Dirk; Hohloch, Stephan published an article in 2021. The article was titled 《Coupling of CO2 and epoxides catalysed by novel N-fused mesoionic carbene complexes of nickel(II)》, and you may find the article in Dalton Transactions.Synthetic Route of C30H30N10 The information in the text is summarized as follows:
Syntheses of two rigid mesoionic carbene (MIC) ligands with a carbazole backbone via an intramol. Finkelstein-cyclization cascade and investigate their coordination behavior toward nickel(II) acetate. Despite the nickel(II) carbene complexes showed only minor differences in their chem. composition, they displayed curious differences in their chem. properties, e.g. solubility Furthermore, the potential of these novel MIC complexes in the coupling of carbon dioxide and epoxides to afford dioxolanone derivatives I [R = OCH2CH=CH2, CH2CH=CH2, NHBOC, etc.] and the differences in reactivity compared to classical NHC-derived complexes were evaluated.Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8Synthetic Route of C30H30N10) was used in this study.
Tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)amine(cas: 510758-28-8) can stabilizes Cu(I) towards disproportionation and oxidation thus enhancing its catalytic effect in the azide-acetylene cycloaddition.Synthetic Route of C30H30N10
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics