Yin, Weiyu published the artcileHighly Practical Synthesis of Nitriles and Heterocycles from Alcohols under Mild Conditions by Aerobic Double Dehydrogenative Catalysis, HPLC of Formula: 143426-50-0, the main research area is alc aerobic double dehydrogenation ammonia nitrile synthesis; biaryl heterocycle one pot synthesis nitrile in situ heterocyclization.
A mild, aerobic, catalytic process for obtaining nitriles directly from alcs. and aqueous ammonia is described (RC6H4CH2OH + NH3 → RC6H4CN). The reaction proceeds via a dehydrogenation cascade mediated by catalytic CuI, bpy, and TEMPO in the presence of O2. The substrate scope is broad including various functionalized aromatic and aliphatic alcs. This protocol enabled the one-pot synthesis of various biaryl heterocycles directly from com. available alcs. (e.g., PhCH2OH + NH3 in first step; addition of ethylenediamine in second step → 2-phenyl-4,5-dihydro-1H-imidazole).
Organic Letters published new progress about Aliphatic alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 143426-50-0 belongs to class triazoles, name is 4-(1,2,4-Triazol-1-yl)benzyl Alcohol, and the molecular formula is C9H9N3O, HPLC of Formula: 143426-50-0.
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics