Huang, Yangen published the artcileHighly dense nitranilates-containing nitrogen-rich cations, Formula: C3H7IN4, the main research area is high density nitrogen heterocycle cation nitranilate explosive; detonation formation enthalpy nitranilate salt explosive.
High d. energetic salts containing nitrogen-rich cations and the nitranilic anion were readily synthesized in high yield by metathesis reactions of sodium nitranilate and an appropriate halide. All of the new compounds were fully characterized by elemental, spectral (IR, 1H, 13C NMR), and thermal (DSC) analyses. The structure of hydrazinium nitranilate was also determined by single-crystal X-ray anal. The high symmetry and oxygen content of the anion give these salts extensive hydrogen bonding capability which further results in the high densities, low water solubilities, and high thermal stabilities (Td >200°) of these compounds Theor. performance calculations were carried out by using Gaussian 03 and Cheetah 5.0. The calculated detonation pressures (P) for these new salts fall between 17.5 GPa and 31.7 GPa, and the detonation velocities (νD) range between 7022 m/s and 8638 m/s.
Chemistry – A European Journal published new progress about Crystal structure (of hydrazinium nitranilate). 39602-93-2 belongs to class triazoles, name is 4-Amino-1-methyl-4H-1,2,4-triazol-1-ium iodide, and the molecular formula is C3H7IN4, Formula: C3H7IN4.
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics