Xue, Hong published the artcileNew Energetic Salts Based on Nitrogen-Containing Heterocycles, Synthetic Route of 39602-93-2, the main research area is azidotriazole iodomethane quaternization; nitric acid azidotriazole quaternization; perchloric acid azidotriazole quaternization; azidotriazolium energetic salt preparation crystal structure formation enthalpy; imidazolium nitrate preparation energetic salt formation enthalpy thermal stability; methyltetrazolium nitrate preparation energetic salt formation enthalpy thermal stability; perchlorate tetrazolium preparation energetic salt formation enthalpy thermal stability.
New energetic salts were synthesized via the quaternization of azido or nitro derivatives of imidazole, 1,2,4-triazole, and substituted derivatives of tetrazole with nitric or perchloric acid or iodomethane followed by metathesis reaction with silver nitrate or silver perchlorate. The structures of 1,4-dimethyl-3-azido-1,2,4-triazolium nitrate (I, R = Me), 3-azido-1,2,4-triazolium nitrate (I, R = H), 1-methyl-4-amino-1,2,4-triazolium perchlorate (II, R = NH2, X = ClO4-), and 1,4-dimethyl-2-H-1,2,4-triazolium triiodide (II, R = Me, X = I3-) were confirmed by single-crystal X-ray anal. Most of the salts exhibit good thermal stabilities and low m.ps. By using constant volume combustion energies that were determined exptl. using an oxygen bomb calorimeter, the standard molar enthalpies of formation were derived based on designed Hess thermochem. cycles.
Chemistry of Materials published new progress about Explosives. 39602-93-2 belongs to class triazoles, name is 4-Amino-1-methyl-4H-1,2,4-triazol-1-ium iodide, and the molecular formula is C3H7IN4, Synthetic Route of 39602-93-2.
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics