Suleimanov, Iurii published the artcileEffect of ligand substitution in [Fe(H-trz)2(trz)]BF4 spin crossover nanoparticles, Computed Properties of 63598-71-0, the publication is French-Ukrainian Journal of Chemistry (2015), 3(1), 66-72, database is CAplus.
Spin crossover iron(II) 1,2,4-triazole-based coordination compounds in the form of nanoparticles were prepared using a reverse microemulsion technique. Ligand substitution approach was applied to decrease the spin crossover temperature towards room temperature in the well-known [Fe(H-trz)2(trz)]BF4 complex. The compositions of the particles were determined by elemental anal. and thermogravimetry. The morphol. was monitored by transition electron microscopy (TEM). The effect associated with the ligand substitution was investigated by optical and magnetic measurements. Transition temperature has been reduced by 33 K comparing the unsubstituted sample to that with 5 % substitution.
French-Ukrainian Journal of Chemistry published new progress about 63598-71-0. 63598-71-0 belongs to triazoles, auxiliary class Triazole, name is 4H-1,2,4-Triazole, and the molecular formula is C13H26N2, Computed Properties of 63598-71-0.
Referemce:
https://en.wikipedia.org/wiki/1,2,3-Triazole,
Triazoles – an overview | ScienceDirect Topics