Shainyan, B. A.’s team published research in Russian Journal of General Chemistry in 85 | CAS: 14544-45-7

Russian Journal of General Chemistry published new progress about 14544-45-7. 14544-45-7 belongs to triazoles, auxiliary class Triazoles, name is 5-Nitro-1H-1,2,3-triazole, and the molecular formula is C14H28O5S, Name: 5-Nitro-1H-1,2,3-triazole.

Shainyan, B. A. published the artcileTriflamidomethyl and oxymethyl derivatives of 1,2,3-triazoles, Name: 5-Nitro-1H-1,2,3-triazole, the publication is Russian Journal of General Chemistry (2015), 85(10), 2309-2312, database is CAplus.

The reactions of some 1,2,3-triazoles with formaldehyde and triflamide have been studied. N-(Hydroxy-methyl)-2-phenyl-2H-1,2,3-triazole-4-carboxamide reacted with triflamide in sulfuric acid to afford 2-phenyl-2H-1,2,3-triazole-4-carboxamide, bis(triflamido)methane, and N,N-bis[(trifluoromethylsulfonyl)aminomethyl]-triflamide. In the presence of K2CO3, 4-amino-5-nitro-2-ethyl-1,2,3-triazole was reduced with hydrazine hydrate to 2-ethyl-2H-1,2,3-triazole-4,5-diamine, and with formaldehyde in the presence of K2CO3, it resulted in N,N-bis(2-ethyl-5-nitro-2H-1,2,3-triaxol-4-yl)methanediamine, which reacted with paraformaldehyde under acidic conditions with the formation of 4-aminomethyl-5-nitro-2-ethyl-1,2,3-triazole.

Russian Journal of General Chemistry published new progress about 14544-45-7. 14544-45-7 belongs to triazoles, auxiliary class Triazoles, name is 5-Nitro-1H-1,2,3-triazole, and the molecular formula is C14H28O5S, Name: 5-Nitro-1H-1,2,3-triazole.

Referemce:
https://en.wikipedia.org/wiki/1,2,3-Triazole,
Triazoles – an overview | ScienceDirect Topics