Gareev, G. A.’s team published research in Zhurnal Organicheskoi Khimii in 27 | CAS: 14544-45-7

Zhurnal Organicheskoi Khimii published new progress about 14544-45-7. 14544-45-7 belongs to triazoles, auxiliary class Triazoles, name is 5-Nitro-1H-1,2,3-triazole, and the molecular formula is C2H2N4O2, Category: triazoles.

Gareev, G. A. published the artcileVinyl ethers of nitramino alcohols, Category: triazoles, the publication is Zhurnal Organicheskoi Khimii (1991), 27(11), 2261-8, database is CAplus.

Vinyl exchange reaction of nitramino alcs. with vinyl acetate catalyzed by Hg(OAc)2 and BF3.Et2O, and also dehydrochlorination of 2-chloroethyl ether of 2-nitro-2-aza-1-propanol by bases in the presence of phase-transfer catalysts or by the reaction of K salts of methylnitramine with vinyl ethers of 2-chloroethanol or ethylene glycol mononitrate gives vinyl ethers containing a nitramine fragment. Electrophilic addition reactions of carboxylic acids and heterocyclic NH-acids at the multiple bond of the vinyl ether of 2-nitro-2-aza-1-propanol were studied. In addition to the normal addition reaction at the multiple bond substitution of the vinyloxy group on the acid residue also takes place. Thus, treating MeN(NO2)CH2OCH:CH2 with azoles I (R = Ph, Me, X = Y = N; R = NO2, X = N, Y = CH; R = NO2, X = CH, Y = N) gave 14-85% azoles II.

Zhurnal Organicheskoi Khimii published new progress about 14544-45-7. 14544-45-7 belongs to triazoles, auxiliary class Triazoles, name is 5-Nitro-1H-1,2,3-triazole, and the molecular formula is C2H2N4O2, Category: triazoles.

Referemce:
https://en.wikipedia.org/wiki/1,2,3-Triazole,
Triazoles – an overview | ScienceDirect Topics