Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 1704-62-7, Name is 2-(2-(Dimethylamino)ethoxy)ethanol, SMILES is CN(CCOCCO)C, belongs to Triazoles compound. In a document, author is Guarnieri-Ibanez, Alejandro, introduce the new discover, COA of Formula: C6H15NO2.
Regiodivergent synthesis of pyrazino-indolines vs. triazocines via alpha-imino carbenes addition to imidazolidines
Hexahydropyrazinoindoles were prepared in a single step from N-sulfonyl triazoles and imidazolidines. Under dirhodium catalysis, alpha-imino carbenes were generated and formed nitrogen ylide intermediates that, after subsequent aminal opening, afforded the pyrazinoindoles predominantly via formal [1,2]-Stevens and tandem Friedel-Crafts cyclizations. Of mechanistic importance, a regiodivergent reactivity was engineered through the use of a specific unsymmetrically substituted imidazolidine that promoted the exclusive formation of 8-membered ring 1,3,6-triazocines. Based on DFT calculations, an original Curtin-Hammett-like situation was demonstrated for the mechanism. Further derivatizations led to functionalized tetrahydropyrazinoindoles in high yields.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1704-62-7 is helpful to your research. COA of Formula: C6H15NO2.