Reference of 584-13-4, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 584-13-4, Name is 4H-1,2,4-Triazol-4-amine, SMILES is C1=NN=C[N]1N, belongs to Triazoles compound. In a article, author is Bagtache, R., introduce new discover of the category.
Synthesis, physical and photo-electrochemical characterizations of a new hybrid host-guest complex [Cu-12(C2N3H2)(8)Cl][(PW12O40)]
Through careful choice of reduction conductions, a new hybrid host-guest compound [Cu-12(C2N3H2)(8)Cl][(PW12O40)] was synthesized hydrothermally in the presence of 1, 2, 4 triazole as structure-directing agent. The material has been characterized by single-crystal X-ray diffraction, chemical analysis, FT-IR spectroscopy, thermal analysis and UV-Vis diffuse reflectance. The compound based on a two-dimensional (2D) supramolecular porous coordination polymer [Cu-12 (C2N3H2)(8)Cl](3+) can accommodate in its cavities the Keggin polyoxotungstate anions, with host-guest interactions crystallizing in the monoclinic system (Space Group: C2/m). The metal organic species and Keggin anions are connected via hydrogen bonds and Cu center dot center dot center dot O short contacts giving rise to a three-dimensional architecture. The optical study shows a direct transition (1.60 eV) assigned to the O2-: 2p -> Cu+: 4 s transition. The transport properties revealed a semiconductor comportment; the thermal variation of log (conductivity) versus 1000/T was fitted by a least square method to a straight line whose slope gave an activation energy of 54 meV. The chrono-amperometry and photo-electrochemistry, carried out in Na2SO4 (0.5 M) electrolyte, indicate n-type conduction with a flat band potential of +0.10 V-SCE, making [Cu-12(C2N3H2)(8)Cl][(PW12O40)] a promising solar material. (C) 2020 Elsevier B.V. All rights reserved.
Reference of 584-13-4, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 584-13-4 is helpful to your research.