An article A Stable Zn-Based Metal-Organic Framework as an Efficient Catalyst for Carbon Dioxide Cycloaddition and Alcoholysis at Mild Conditions WOS:000499226600003 published article about CHEMICAL FIXATION; CO2; PERFORMANCE; SEPARATION; POLYMER; MOF; MG in [Luo, Zhiqiang; Wang, Jun; He, Yanqing; Ao, Qiong; Deng, Qiang; Zeng, Zheling] Nanchang Univ, Minist Educ, Key Lab Poyang Environm & Resource Utilizat, Nanchang 330031, Jiangxi, Peoples R China; [Luo, Zhiqiang; Wang, Jun; He, Yanqing; Ao, Qiong; Deng, Qiang; Zeng, Zheling] Nanchang Univ, Sch Resource Environm & Chem Engn, Nanchang 330031, Jiangxi, Peoples R China; [Wang, Hongming] Nanchang Univ, Inst Adv Study, Nanchang 330031, Jiangxi, Peoples R China; [Deng, Shuguang] Arizona State Univ, Sch Engn Matter Transport & Energy, 551 E Tyler Mall, Tempe, AZ 85287 USA in 2020.0, Cited 31.0. Name: 1H-1,2,4-Triazol-5-amine. The Name is 1H-1,2,4-Triazol-5-amine. Through research, I have a further understanding and discovery of 61-82-5
Developing highly efficient heterogeneous catalysts for cycloaddition of CO2 and epoxides to produce cyclic carbonates is promising but challenging. In this work, a novel three-dimensional metal organic framework (MOF) with cylinder pore systems and unsaturated Zn sites has been demonstrated as potent candidate in CO2 fixation at mild and solvent-free conditions. The Zn(atz)(bdc)(0.5), where atz = aminotriazole and H(2)bdc = terephthalic, exhibits microporous nature that can regulate the catalytic interaction of active centers and substrates. The structure stability has been systematically investigated and proven to be sufficient for practical application. Furthermore, the cooperative effects of porosity, CO2 binding affinity, activation centers, and synergism with co-catalyst have been deeply investigated. Moreover, high propylene epoxide conversion (97%) and selectivity (> 99%) have been achieved at mild conditions (60 degrees C and 1 MPa) with excellent cycle stability. Owing to the well-defined pore system, an obvious substrates selectivity has been clearly observed. A possible catalytic mechanism has been proposed and verified by DFT calculations. Furthermore, the prepared Zn-MOF can also be used as an efficient heterogeneous catalyst for the reaction of epoxides with alcohols to produce beta-alkoxy alcohol. [GRAPHICS] .
Name: 1H-1,2,4-Triazol-5-amine. Bye, fridends, I hope you can learn more about C2H4N4, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Article; Safari, Niloufar; Shirini, Farhad; Tajik, Hassan; Journal of Molecular Structure; vol. 1201; (2020);,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics