Category: 157069-48-2

Song, Jiang-Feng et al. published their research in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2011 | CAS: 157069-48-2

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Triazoles are important five-member nitrogen heterocycles involved in a wide range of industrial applications such as agrochemicals, corrosion inhibitors, dyes, optical brighteners, as well as biologically active agents. The presence of the three nitrogen atoms in triazole structures afforded opportunities for a plethora of structural modification with the generation of novel therapeutically potential agents, which is different from other heterocyclic compounds.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Three New cpt-Metal Complexes Displaying 0D, 1D, and 3D Topology Structures was written by Song, Jiang-Feng;Zhou, Rui-Sha;Zhang, Jia;Xu, Chun-Yan;Li, Yan-Bing;Wang, Biao-Bing. And the article was included in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2011.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid This article mentions the following:

Three new cpt-metal complexes of different topol. structures were synthesized by solvothermal methods (Hcpt = 4-(4-carboxyphenyl)-1,2,4-triazole). The structure of [Mn(cpt)2·2H2O] (1) is essentially 0-dimensional monomeric, but extended into a 2-dimensional supramol. network through crosslinking hydrogen bonds. In [Cu(cpt)(OH)·2H2O]·2H2O (2), the hydroxo groups as well as cpt ligands join the copper ions into an infinite polymeric [Cu(μ-cpt)(μ-OH)] chain, which is interconnected into a 3-dimensional supramol. network with different oriented channels by 1-dimensional water chains. [Zn(cpt)2]·0.5DMF·CH3CH2OH (3), which crystallizes in a 3-dimensional open framework with 4-fold interpenetrated diamondoid network topol., represents the 1st 3-dimensional structure based on cpt anions. The structure differences demonstrate that the reaction metal ions have an important effect on the structures of these complexes. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Triazoles are important five-member nitrogen heterocycles involved in a wide range of industrial applications such as agrochemicals, corrosion inhibitors, dyes, optical brighteners, as well as biologically active agents. The presence of the three nitrogen atoms in triazole structures afforded opportunities for a plethora of structural modification with the generation of novel therapeutically potential agents, which is different from other heterocyclic compounds.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Chen, Di-ming et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2015 | CAS: 157069-48-2

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Both the triazoles and their derivatives have significant biological properties including antimicrobial, antiviral, antitubercular, anticancer, anticonvulsant, analgesic, antioxidant, anti-inflammatory, and antidepressant activities.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

A cage-based cationic body-centered tetragonal metal-organic framework: single-crystal to single-crystal transformation and selective uptake of organic dyes was written by Chen, Di-ming;Shi, Wei;Cheng, Peng. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2015.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid This article mentions the following:

A cage-based cationic body-centered metal-organic framework, {[(Cu4Cl)(CPT)4(H2O)4]·3NO3·5NMP·3.5H2O} (1)(HCPT = 4-(4-carboxyphenyl)-1,2,4-triazole, NMP = N-methyl-2-pyrrolidone), was successfully synthesized using a custom-designed bifunctional triazolcarboxylate ligand. It shows interesting single-crystal-to-single-crystal transformation upon solvent exchange process and selective uptake of organic dyes. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Both the triazoles and their derivatives have significant biological properties including antimicrobial, antiviral, antitubercular, anticancer, anticonvulsant, analgesic, antioxidant, anti-inflammatory, and antidepressant activities.Recommanded Product: 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Lysenko, Andrey B. et al. published their research in Inorganic Chemistry in 2017 | CAS: 157069-48-2

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. 1,2,3-Triazoles are usually prepared following (3+2) cycloaddition protocols. A common technique for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However, the Huisgen strategy produces a mixture of isomers (typically 1,4- and 1,5-disubstituted) when used to produce substituted triazoles.Application In Synthesis of 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Triazolyl, Imidazolyl, and Carboxylic Acid Moieties in the Design of Molybdenum Trioxide Hybrids: Photophysical and Catalytic Behavior was written by Lysenko, Andrey B.;Senchyk, Ganna A.;Domasevitch, Konstantin V.;Kobalz, Merten;Krautscheid, Harald;Cichos, Jakub;Karbowiak, Miroslaw;Neves, Patricia;Valente, Anabela A.;Goncalves, Isabel S.. And the article was included in Inorganic Chemistry in 2017.Application In Synthesis of 4-(4H-1,2,4-Triazol-4-yl)benzoic acid This article mentions the following:

Three organic ligands bearing 1,2,4-triazolyl donor moieties, (S)-4-(1-phenylpropyl)-1,2,4-triazole (trethbz), 4-(1,2,4-triazol-4-yl)benzoic acid (trPhCO2H), and 3-(1H-imidazol-4-yl)-2-(1,2,4-triazol-4-yl)propionic acid (trhis), were prepared to evaluate their coordination behavior in the development of Mo(VI) oxide organic hybrids. Four compounds, [Mo2O6(trethbz)2]·H2O (1), [Mo4O12(trPhCO2H)2]·0.5H2O (2a), [Mo4O12(trPhCO2H)2]·H2O (2b), and [Mo8O25(trhis)2(trhisH)2]·2H2O (3), were synthesized and characterized. The monofunctional tr-ligand gave a zigzag chain [Mo2O6(trethbz)2] built up from cis-{MoO4N2} octahedra united through common μ2-O vertexes. Employing the heterodonor ligand with tr/-CO2H functions afforded either layer or ribbon structures of corner- or edge-sharing {MoO5N} polyhedra (2a or 2b) stapled by tr-links in axial positions, whereas -CO2H groups remained uncoordinated. The presence of the imidazole-heterocycle as an extra function in trhis facilitated formation of zwitterionic mols. with a protonated imidazolium group (imH+) and a neg. charged -CO2– group, whereas the tr-fragment was left neutral. Under the acidic hydrothermal conditions used, the organic ligand binds to Mo atoms either through [N-N]-tr or through both [N-N]-tr and μ2-CO2– units, which occur in protonated bidentate or zwitterionic tetradentate forms (trhisH+ and trhis, resp.). This leads to a new zigzag subtopol. motif (3) of neg. charged polyoxomolybdate {Mo8O25}n2n- consisting of corner- and edge-sharing cis-{MoO4N2} and {MoO6} octahedra, while the tetradentate zwitterionic trhis species connect these chains into a 2D net. Electronic spectra of the compounds showed optical gaps consistent with semiconducting behavior. The compounds were studied as epoxidation catalysts via the model reactions of achiral and prochiral olefins (cis-cyclooctene and trans-β-methylstyrene) with tert-Bu hydroperoxide. The best-performing catalyst (1) was explored for the epoxidation of other olefins, including biomass-derived Me oleate, Me linoleate, and prochiral DL-limonene. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Application In Synthesis of 4-(4H-1,2,4-Triazol-4-yl)benzoic acid).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. 1,2,3-Triazoles are usually prepared following (3+2) cycloaddition protocols. A common technique for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However, the Huisgen strategy produces a mixture of isomers (typically 1,4- and 1,5-disubstituted) when used to produce substituted triazoles.Application In Synthesis of 4-(4H-1,2,4-Triazol-4-yl)benzoic acid

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics