Category: 288-36-8

Ma, Dong; Yin, Yang; Chen, Ying-Lu; Yan, Yi-Tao; Wu, Jun published an article in 2021. The article was titled 《Design, step-economical diversity-oriented synthesis of an N-heterocyclic library containing a pyrimidine moiety: discovery of novel potential herbicidal agents》, and you may find the article in RSC Advances.Application of 288-36-8 The information in the text is summarized as follows:

The step-economical diversity-oriented synthesis of a library of various pyrimidine-N-heterocycle hybrids I [R = 1H-imidazol-1-yl, 1H-1,2,3-triazol-1-yl, 1-methyl-1H-indol-3-yl, etc.] and II [R1 = 5-Me, 4-Cl, 5-Cl, 6-Cl] was developed, in which a 4,6-dimethoxypyrimidine core was incorporated into nine kinds of N-heterocycles. A total of 34 structurally diverse compounds I and II were synthesized via a two-step process from very simple and com. available starting materials. Further, in-vivo biol. screening of this library identified 11 active compounds I [R = 1H-imidazol-1-yl, 1H-1,2,3-triazol-1-yl, 2-(trifluoromethyl)-1H-1,3-benzodiazol-1-yl, 3-methyl-1H-indazol-1-yl, 5-methyl-1H-indazol-1-yl, 2,3,4,9-tetrahydro-1H-carbazol-9-yl, 1H-indol-3-yl, 4-chloro-1H-indol-3-yl, 5-chloro-1H-indol-3-yl, 7-chloro-1H-indol-3-yl] and II [R1 = 5-Cl] that exhibited good post-emergence herbicidal activity against D. sanguinalis at 750 g ai per ha. More importantly, pyrimidine-tetrahydrocarbazole hybrid I [R = 2,3,4,9-tetrahydro-1H-carbazol-9-yl] showed good to excellent herbicidal activity against five test weeds at the same dosage. Pyrimidine-tetrahydrocarbazole hybrids I [R = 9H-carbazol-9-yl, 2,3,4,9-tetrahydro-1H-carbazol-9-yl, 3-chloro-9H-carbazol-9-yl] represented a novel class of herbicidal agents that may become promising lead compounds in the herbicidal discovery process.1H-1,2,3-Triazole(cas: 288-36-8Application of 288-36-8) was used in this study.

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Application of 288-36-8

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Cui, Xue; Ma, Jianting; Zeng, Tingting; Xu, Junyu; Li, Youbin; Wang, Xuesong published their research in RSC Advances in 2021. The article was titled 《Metal-free cascade synthesis of unsymmetrical 2-aminopyrimidines from imidazolate enaminones》.Formula: C2H3N3 The article contains the following contents:

A convenient metal-free synthesis of unsym. 2-aminopyrimidines I [R1 = cyclopropyl, Ph, 4-MeC6H4, etc.; R2 = Ph, 4-ClC6H4, 4-MeOC6H4, etc.] from imidazolate enaminones had been developed. In this procedure, various structural 2-aminopyrimidines I, as well as 4,5-dihydroisoxazol-5-ols and pyrazoles were synthesized in moderate to excellent yields. A plausible mechanism was also proposed for the cascade reaction. This method represented an effective strategy toward the synthesis of unsym. 2-aminopyrimidines I. In the part of experimental materials, we found many familiar compounds, such as 1H-1,2,3-Triazole(cas: 288-36-8Formula: C2H3N3)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Formula: C2H3N3

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

《Molybdenum oxide-based metal-organic framework/polypyrrole nanocomposites for enhancing electrochemical detection of dopamine》 was written by Zhou, Kunfeng; Shen, Defeng; Li, Xiao; Chen, Yuhao; Hou, Liran; Zhang, Yishuai; Sha, Jingquan. Quality Control of 1H-1,2,3-Triazole And the article was included in Talanta in 2020. The article conveys some information:

To overcome the poor conductivities and promote the application in the biosensors of metal-organic frameworks (MOFs), a simple approach was employed to improve their overall conductivity by adjusting the metal centers of MOFs and coating conductive polypyrrole (PPy) in the work. An unprecedented molybdenum oxide-based three-dimensional MOFs with helical channels (CuTRZMoO4) was synthesized based on MoO-4, Cu2+ ions and 1,2,3-trz for the first time, then combined with PPy to fabricate hybrid composites (CuTRZMoO4@PPy-n) with both advantages. The CuTRZMoO4 modified glassy carbon electrode show high sensitivity for detecting the neurotransmitter dopamine (DA), and the CuTRZMoO4@PPy-2 modified glassy carbon electrode has the highest catalytic activity to DA with the linear detection range from 1μM to 100μM and the detection limit of 80 nM (S/N = 3) by differential pulse voltammetry (DPV). Moreover, the developed biosensor has good selectivity, reproducibility and stability. The concept behind the new architecture to modify electrodes should promote the further development of MOF-based biosensors. In the experiment, the researchers used 1H-1,2,3-Triazole(cas: 288-36-8Quality Control of 1H-1,2,3-Triazole)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Quality Control of 1H-1,2,3-Triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

《Energetic metal-organic frameworks derived highly nitrogen-doped porous carbon for superior potassium storage》 was written by Tong, Huigang; Wang, Changlai; Lu, Jian; Chen, Shi; Yang, Kang; Huang, Minxue; Yuan, Qing; Chen, Qianwang. Electric Literature of C2H3N3 And the article was included in Small in 2020. The article conveys some information:

The carbonaceous materials with low cost and high safety have been considered as promising anodes for potassium-ion batteries (PIBs). However, it is still a challenge to design a carbonaceous material with long cycle life and high rate performance due to the poor K+ reaction kinetics. Herein, this article reports a N-doped porous carbon framework (NPCF) with a high nitrogen content of 13.57 at% within high doping level of the pyrrolic N and pyridinic N, which exhibits a high reversible capacity of 327 mA h g-1 over 100 cycles at a c.d. of 100 mA g-1, excellent rate capability (144 and 105 mA h g-1 at 10 and 20 A g-1, resp.) and great cyclability of 258.9 mA h g-1 after 2000 cycles at 1 A g-1. Such a high rate performance and excellent cycling stability anode material is seldom reported in PIBs. D. functional theory (DFT) calculations reveal that the pyrrolic and pyridinic N-doping are helpful to enhance the K adsorption ability, thereby increasing the specific capacity. In addition to this study using 1H-1,2,3-Triazole, there are many other studies that have used 1H-1,2,3-Triazole(cas: 288-36-8Electric Literature of C2H3N3) was used in this study.

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Electric Literature of C2H3N3

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

In 2022,Wu, Yingxiao; Cheng, Jinqian; Liang, Zibin; Tang, Yanqun; Qiu, Tianjie; Gao, Song; Zhong, Ruiqin; Zou, Ruqiang published an article in Small. The title of the article was 《Puffing Up Hollow Carbon Nanofibers with High-Energy Metal-Organic Frameworks for Capacitive-Dominated Potassium-Ion Storage》.Reference of 1H-1,2,3-Triazole The author mentioned the following in the article:

Nitrogen-doped carbon materials with abundant defects and strong potassium adsorption ability have been recognized as potential anodes for potassium ion batteries (PIBs). However, the limited content and uncontrolled type of nitrogen-doped sites hinder the further performance improvement of PIBs. Herein, this work proposes nitrogen phosphorous co-doped hollow carbon nanofibers (PNCNFs) derived from high-energy metal-organic frameworks (MOFs) with an ultra-high nitrogen content of 19.52 wt% and a high portion of more reactive pyridinic N sites. Furthermore, the highly open architecture exploded by released gases from high-energy MOFs provides sufficient edge sites to settle the N atoms and further form pyridinic N sites induced by phosphorous dopants. The resulting PNCNFs achieve excellent potassium ion storage performance with high reversible capacity (466.2 mAh g-1), superb rate capability (244.4 mAh g-1 at 8 A g-1), and excellent cycling performance (294.6 mAh g-1 after 3250 cycles). The d. functional theory calculation reveals that the N/P defects enhance the potassium adsorption ability and improve the conductivity The experimental process involved the reaction of 1H-1,2,3-Triazole(cas: 288-36-8Reference of 1H-1,2,3-Triazole)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Reference of 1H-1,2,3-Triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Application In Synthesis of 1H-1,2,3-TriazoleIn 2020 ,《Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material》 was published in Chem. The article was written by Li, Xuning; Cao, Chang-Su; Hung, Sung-Fu; Lu, Ying-Rui; Cai, Weizheng; Rykov, Alexandre I.; Miao, Shu; Xi, Shibo; Yang, Hongbin; Hu, Zehua; Wang, Junhu; Zhao, Jiyong; Alp, Esen Ercan; Xu, Wei; Chan, Ting-Shan; Chen, Haoming; Xiong, Qihua; Xiao, Hai; Huang, Yanqiang; Li, Jun; Zhang, Tao; Liu, Bin. The article contains the following contents:

The lack of model single-atom catalysts (SACs) and at.-resolution operando spectroscopic techniques greatly limits our comprehension of the nature of catalysis. Herein, based on the designed model single-Fe-atom catalysts with well-controlled microenvironments, we have explored the exact structure of catalytic centers and provided insights into a spin-crossover-involved mechanism for oxygen reduction reaction (ORR) using operando Raman, X-ray absorption spectroscopies, and the developed operando57Fe Mossbauer spectroscopy. In combination with theor. studies, the N-FeN4C10 moiety is evidenced as a more active site for ORR. Moreover, the potential-relevant dynamic cycles of both geometric structure and electronic configuration of reactive single-Fe-atom moieties are evidenced via capturing the peroxido (*O-2) and hydroxyl (*OH-) intermediates under in situ ORR conditions. We anticipate that the integration of operando techniques and SACs in this work shall shed some light on the electronic-level insight into the catalytic centers and underlying reaction mechanism. In the experimental materials used by the author, we found 1H-1,2,3-Triazole(cas: 288-36-8Application In Synthesis of 1H-1,2,3-Triazole)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Application In Synthesis of 1H-1,2,3-Triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

In 2022,Jiang, Zi-Yu; Huang, Zhe-Yao; Yang, Hong; Zhou, Lin; Li, Qing-Han; Zhao, Zhi-Gang published an article in RSC Advances. The title of the article was 《Cs2CO3 catalyzed direct aza-Michael addition of azoles to α,β-unsaturated malonates》.Recommanded Product: 1H-1,2,3-Triazole The author mentioned the following in the article:

A highly efficient method for the synthesis of pyrazole derivatives I (R1 = Pr, Ph, 2-furyl, etc.; R2 = Me, Et, iso-Pr, tert-butyl; R3 = H, Cl, Me, Br; R4 = H, Me, Br) and some other azole derivatives e.g., II via a direct aza-Michael addition of azoles – pyrazole/e.g., 1H-1,2,3-triazole to α,β-unsaturated malonates R1HC=C(C(O)2R2)2 using Cs2CO3 as a catalyst, has been successfully developed. A series of azole derivatives have been obtained in up to 94% yield and the reaction could be amplified to gram scale in excellent yield in the presence of 10 mol% of Cs2CO3.1H-1,2,3-Triazole(cas: 288-36-8Recommanded Product: 1H-1,2,3-Triazole) was used in this study.

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Recommanded Product: 1H-1,2,3-Triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Cui, Menghan; Su, Changhui; Wang, Rong; Yang, Qing; Kuang, Chunxiang published their research in RSC Advances in 2021. The article was titled 《Synthesis of vinyl-1,2,3-triazole derivatives under transition metal-free conditions》.Name: 1H-1,2,3-Triazole The article contains the following contents:

A novel and green route for the direct synthesis of vinyl triazole derivatives with alkynes and triazoles promoted by an inorganic base under transition metal-free conditions was described. The base showed great catalytic activity for the anti-Markovnikov stereoselective hydroamination of alkynes. Moreover, good yields with excellent functional group tolerance were successfully achieved for a range of substrates, including aryl and heteroaryl groups, terminal alkynes and internal alkynes, and various triazole derivatives This work presented an advanced concept for the synthesis of alkenyl triazole with a versatile and cost-efficient approach. In the part of experimental materials, we found many familiar compounds, such as 1H-1,2,3-Triazole(cas: 288-36-8Name: 1H-1,2,3-Triazole)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Name: 1H-1,2,3-Triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

《Synthesis of a Water-Soluble, Soft N-Donor BTzBP Ligand Containing Only CHON》 was published in Synlett in 2020. These research results belong to Labb, Samantha A.; Masteran, Conner J.; Albright, Savannah G.; Ali, Bakr; Chapman, Hayley A.; Cheng, Yijie; Cusic, Rachel M.; Hartlove, Nathan B.; Marr, Alissa N.; Timmons, Miranda; Friese, Seth J.. Application of 288-36-8 The article mentions the following:

A hydrophilic ligand that contains only C, H, O, and N substituents and uses a 6,6′-bis(1 H-1,2,3-triazol-4-yl)-2,2′-bipyridine (BTzBP) structural core has been synthesized. The effect of adding water-soluble groups onto extractant ligands has been extensively studied to facilitate the efficient partitioning of 4f and transuranic 5f elements for the treatment of spent nuclear fuel. Soft, N-donor ligands exhibit greater binding affinities for the trivalent actinides over the trivalent lanthanides, making BTzBP ligands an ideal candidate in the search for extractants to be used on an industrial scale. To date, hydrophobic BTzBPs have been shown to exhibit phys. and chem. properties that might be conducive to nuclear waste processing conditions. However, hydrophilic BTzBPs have yet to be reported. Herein, we show the synthesis of a hydrophilic BTzBP ligand featuring cationic water solubilizing groups attached to the bipyridyl rings. In the part of experimental materials, we found many familiar compounds, such as 1H-1,2,3-Triazole(cas: 288-36-8Application of 288-36-8)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Application of 288-36-8

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Li, Xuning; Zeng, Yaqiong; Tung, Ching-Wei; Lu, Ying-Rui; Baskaran, Sambath; Hung, Sung-Fu; Wang, Shifu; Xu, Cong-Qiao; Wang, Junhu; Chan, Ting-Shan; Chen, Hao Ming; Jiang, Jianchao; Yu, Qi; Huang, Yanqiang; Li, Jun; Zhang, Tao; Liu, Bin published an article in 2021. The article was titled 《Unveiling the In Situ Generation of a Monovalent Fe(I) Site in the Single-Fe-Atom Catalyst for Electrochemical CO2 Reduction》, and you may find the article in ACS Catalysis.Computed Properties of C2H3N3 The information in the text is summarized as follows:

Atomically dispersed single-atom catalysts are among the most attractive electrocatalysts for the CO2 reduction reaction (CRR). To elucidate the origin of the exceptional activity of atomically dispersed Fe-N-C catalyst in CRR, we have performed operando 57Fe Mössbauer spectroscopic studies on a model single-Fe-atom catalyst with a well-defined N coordination environment. Combining with operando X-ray absorption spectroscopy, the in situ-generated four pyrrolic nitrogen atom-coordinated low-spin Fe(I) (LS FeIN4) featuring monovalent iron is identified as the reactive center for the conversion of CO2 to CO. Furthermore, d. functional theory calculations reveal that the optimal binding strength of CO2 to the LS FeIN4 site, with strong orbital interactions between the singly occupied dz2 orbital of the Fe(I) site and the singly occupied π* orbital of [COOH] fragment, is the key factor for the excellent CRR performance. After reading the article, we found that the author used 1H-1,2,3-Triazole(cas: 288-36-8Computed Properties of C2H3N3)

1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Computed Properties of C2H3N3

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics