Category: 5301-96-2

On March 5, 1990, Ito, Suketaka; Kakehi, Akikazu; Yamazaki, Akihiro published an article.COA of Formula: C9H9N3 The title of the article was Thermolysis of α-azidoacetophenone phenylsulfonylhydrazones. A new preparative route to 4-aryl-1H-1,2,3-triazoles. And the article contained the following:

Thermolysis of α-azidoacetophenone phenylsulfonylhydrazones 4-R(C6H4C(CH2N3):NNHSO2Ph (R = H, Br, Cl, NO2, Me, Ph, PhN:N) gave 4-aryl-1H-1,2,3-triazoles I in good yields. The reaction proceeds probably via the elimination of benzenesulfinic acid from 4-aryl-2-phenylsulfonyltriazolines formed intermediately. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).COA of Formula: C9H9N3

The Article related to azidoacetophenone phenylsulfonylhydrazone thermolysis, cyclization azidoacetophenone phenylsulfonylhydrazone, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.COA of Formula: C9H9N3

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On January 25, 2017, Bhagat, Ujjawal Kumar; Kamaluddin; Peddinti, Rama Krishna published an article.Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole The title of the article was DABCO-mediated aza-Michael addition of 4-aryl-1H-1,2,3-triazoles to cycloalkenones. Regioselective synthesis of disubstituted 1,2,3-triazoles. And the article contained the following:

Aza-Michael addition of 4-aryl-1H-1,2,3-triazoles to 2-cycloalken-1-ones was studied in the presence of DABCO as organic base. The reactions were carried out in acetonitrile at room temperature to provide 2,4-disubstituted 2H-1,2,3-triazoles I [R = H, Me; Ar = C6H5, 4-MeC6H4, 2-MeO-1-naphthyl, etc.; n = 1] as major adducts and 1,4-disubstituted 1H-1,2,3-triazoles II [n = 0] as minor adducts. Though the reaction times are longer (4-8 days), the two regioisomers were separated by using column chromatog. and the adducts were obtained in very good to excellent combined chem. yields. The electron-rich and electron-poor substituents on aryl moiety of 4-aryl-triazoles could tolerate the reaction conditions to afford the title adducts. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole

The Article related to disubstituted triazole regioselective preparation, aryl triazole cycloalkenone aza michael addition dabco mediated, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On January 15, 2010, Zhang, Wensheng; Kuang, Chunxiang; Yang, Qing published an article.Application of 5301-96-2 The title of the article was Palladium-catalyzed one-pot synthesis of 4-aryl-1H-1,2,3-triazoles from anti-3-aryl-2,3-dibromopropanoic acids and sodium azide. And the article contained the following:

4-Aryl-1H-1,2,3-triazoles were synthesized from anti-3-aryl-2,3-dibromopropanoates and NaN3 by a 1-pot method using DMF as solvent in the presence of tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3] and Xantphos. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Application of 5301-96-2

The Article related to bromopropanoate sodium azide heterocyclization palladium catalyst, brominated cinnamate sodium azide heterocyclization palladium catalyst, triazole aryl preparation, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Application of 5301-96-2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On January 16, 2015, Quan, Xue-Jing; Ren, Zhi-Hui; Wang, Yao-Yu; Guan, Zheng-Hui published an article.Name: 4-(p-Tolyl)-1H-1,2,3-triazole The title of the article was p-Toluenesulfonic Acid Mediated 1,3-Dipolar Cycloaddition of Nitroolefins with NaN3 for Synthesis of 4-Aryl-NH-1,2,3-triazoles [Erratum to document cited in CA161:682131]. And the article contained the following:

On page 5730, structure 4a in Scheme 2 was published incorrectly, and subsequent text corresponding to this Structure is also incorrect; the correct structure, name, and text are given. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Name: 4-(p-Tolyl)-1H-1,2,3-triazole

The Article related to erratum aryltriazole preparation toluenesulfonic acid mediated dipolar cycloaddition, dipolar cycloaddition nitroolefin sodium azide aryltriazole preparation erratum, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Name: 4-(p-Tolyl)-1H-1,2,3-triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On November 7, 2014, Liu, Zhenquan; Zhu, Daqian; Luo, Bingling; Zhang, Naiyuan; Liu, Qi; Hu, Yumin; Pi, Rongbiao; Huang, Peng; Wen, Shijun published an article.Category: triazoles The title of the article was Mild Cu(I)-Catalyzed Cascade Reaction of Cyclic Diaryliodoniums, Sodium Azide, and Alkynes: Efficient Synthesis of Triazolophenanthridines. And the article contained the following:

Linear iodoniums are widely used as arylating reagents. However, cyclic diaryl iodoniums are ignored despite their potential to initiate dual arylations, atom and step economically. In our current work, a three-component cascade reaction of cyclic diaryliodoniums, sodium azide, and alkynes has been successfully achieved under mild conditions, catalyzed by cheap copper species. The regioselectivity associated with unsym. iodoniums was enhanced by installing two methyls ortho and para to the IIII center. The reaction enables a rapid access to a variety of complex mols., triazolophenanthridine derivatives I [R1 = H, OMe, Me, etc.; R2 = H, OMe, Me, etc.; R3 = ph, 4-Me-ph, 4-F-ph, etc.]. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Category: triazoles

The Article related to cyclic diaryliodonium sodium azide alkyne, tandem azidation azide alkyne cycloaddition ullmann coupling copper catalyst, triazolophenanthridine preparation, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Category: triazoles

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On November 7, 2014, Quan, Xue-Jing; Ren, Zhi-Hui; Wang, Yao-Yu; Guan, Zheng-Hui published an article.Safety of 4-(p-Tolyl)-1H-1,2,3-triazole The title of the article was p-Toluenesulfonic Acid Mediated 1,3-Dipolar Cycloaddition of Nitroolefins with NaN3 for Synthesis of 4-Aryl-NH-1,2,3-triazoles. And the article contained the following:

A p-TsOH-mediated 1,3-dipolar cycloaddition of nitroolefins and sodium azide for the synthesis of 4-aryl-NH-1,2,3-triazoles has been developed. p-TsOH was discovered as a vital additive in this type of 1,3-dipolar cycloaddition This novel cycloaddition reaction is a good method for the rapid synthesis of valuable 4-aryl-NH-1,2,3-triazoles in high yields. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Safety of 4-(p-Tolyl)-1H-1,2,3-triazole

The Article related to aryltriazole preparation toluenesulfonic acid mediated dipolar cycloaddition, dipolar cycloaddition nitroolefin sodium azide aryltriazole preparation, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Safety of 4-(p-Tolyl)-1H-1,2,3-triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On December 1, 2017, Kang, Taewon; Kim, Hongsik; Lee, Dongwhan published an article.Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole The title of the article was Triazoliptycenes: A Twist on Iptycene Chemistry for Regioselective Cross-Coupling To Build Nonstacking Fluorophores. And the article contained the following:

Triazoliptycene fluorophores have been designed and synthesized, in which a three-dimensional propeller-like iptycene motif is employed to suppress intermol. π-π stacking in the solid state. Key to the success of this modular synthesis is a stereoelectronic bias imposed by the iptycene scaffold, which assists the desired regioselectivity in the C-N cross-coupling step as the last-stage structure diversification from a common precursor. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole

The Article related to crystal mol structure triazoliptycene fluorophore, triazoliptycene modular preparation regioselective coupling nonstacking fluorophore, Heterocyclic Compounds (More Than One Hetero Atom): Other 5-Membered Rings, Two Or More Hetero Atoms and other aspects.Application In Synthesis of 4-(p-Tolyl)-1H-1,2,3-triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On December 18, 2018, Xia, Liangwen; Wang, Xianggang; Xia, Yuchun published a patent.COA of Formula: C9H9N3 The title of the patent was Chromium-free passivator and application thereof. And the patent contained the following:

The present invention discloses a chromium-free passivator and application thereof, which has no toxic and side effects on human body and operating environment, and is very suitable for pre-spraying treatment of aluminum profiles. The chromium-free passivator comprises the following components in percentage by weight: hydrofluoric acid 20-40%, nitric acid 20-30%, fluoro zirconic acid 15-25%, sodium nitrate 2-8%, sodium sulfate 3-6%, nitrogen-containing heterocyclic compounds 2-5%, trisodium hydroxyethyl diamine tetraacetate 2-5%, and diethylene glycol Bu ether 3-14%, when using, mixing with running water to form passivation tank liquid The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).COA of Formula: C9H9N3

The Article related to chromium free passivator passivation tank liquid, Nonferrous Metals and Alloys: Surface Treatment, Metallic and Nonmetallic Coating, Sealing, Cleaning, Polishing, Etching, and Pickling and other aspects.COA of Formula: C9H9N3

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

On April 20, 2018, Lee, Heejin; Lee, Jae Kyun; Min, Sun-Joon; Seo, Hyeonglim; Lee, Youngbok; Rhee, Hakjune published an article.HPLC of Formula: 5301-96-2 The title of the article was Copper(I)-Catalyzed Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Azidoformates and Aryl Terminal Alkynes. And the article contained the following:

The copper(I)-catalyzed azide-alkyne cycloaddition reaction has been extensively studied and widely applied in organic synthesis. However, the formation of 1,2,3-triazoles with electron-deficient azide has been a challenging problem. In this report, we have demonstrated the formation of regioselective 1,4-disubstituted 1,2,3-triazoles from various types of aryl terminal alkynes and azidoformates, which are electron-deficient azides, using a commercialized [Cu(CH3CN)4]PF6 copper(I) catalyst under mild conditions. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).HPLC of Formula: 5301-96-2

The Article related to triazole regioselective preparation cycloaddition azidoformate aryl terminal alkyne, azide alkyne cycloaddition azidoformate aryl terminal alkyne, crystal structure phenyl triazole carboxylate and other aspects.HPLC of Formula: 5301-96-2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics

Bagheri, Sepideh; Nejad, Masoumeh Jadidi; Pazoki, Farzane; Miraki, Maryam Kazemi; Heydari, Akbar published an article in 2019, the title of the article was Folic-Acid-Functionalized Magnetic Nanoparticles as Green and Magnetic Recyclable Catalyst for the Synthesis of 4-Aryl-NH-1,2,3-triazoles in a Green Media.Recommanded Product: 4-(p-Tolyl)-1H-1,2,3-triazole And the article contains the following content:

A useful, robust, and cheap procedure was obtained for the synthesis of 4-aryl-NH-1,2,3-triazoles via aromatic aldehydes, nitromethane and choline azide in the presence of folic acid immobilized magnetic nanoparticle with good yields. The magnetic catalyst was easily synthesized and can be recycled at least five times with no significant loss in activity. In addition, the choline azide was used as a reagent and green solvent. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Recommanded Product: 4-(p-Tolyl)-1H-1,2,3-triazole

The Article related to reusable folic acid functionalize iron oxide catalyst preparation property, aromatic aldehyde nitromethane choline azide iron oxide catalyst cycloaddition, aryltriazole preparation green chem and other aspects.Recommanded Product: 4-(p-Tolyl)-1H-1,2,3-triazole

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics