Series of novel 3D microporous heterometallic 3d-4f coordination frameworks with (5,6)-connected topology. Synthesis, crystal structure and magnetic properties was written by Chen, Chu Jun;Wang, Ning;Long, Yi;Gao, Jin Ying;Xie, Wei Ping;Ran, Xing Rui;Yue, Shan Tang. And the article was included in CrystEngComm in 2013.Application of 4546-95-6 This article mentions the following:
The hydrothermal reaction of rare earth nitrates, CuCN, 1H-1,2,3-triazole-4,5-dicarboxylic acid (H3tda), and isonicotinic acid (Hina) resulted in the formation of a new series of 3d-4f heterometallic coordination polymers [LnCu(tda)(ina)2(H2O)]·3H2O (Ln = Eu (1), Tb (2), Gd (3), Dy (4), Ho (5), H3tda = 1H-1,2,3-triazole-4,5-dicarboxylic acid, Hina = isonicotinic acid). Complexes 1–5 are isostructural and structurally characterized by elemental anal., FT-IR spectroscopy, thermogravimetric anal. (TGA), and single-crystal powder x-ray diffraction (PXRD). Single-crystal x-ray diffraction anal. reveals that the metal cations in these compounds are firstly interconnected by H3tda ligands to produce a carpet-shaped heterometallic ring [Ln2(tda)2Cu4], and then pillared by bridging Hina mols. to form the 3D layer-pillared porous Ln(III)-Cu(II) heterometallic coordination polymers. In addition, the magnetic properties of 1–5 were also investigated in detail. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Application of 4546-95-6).
1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. Triazoles are important five-member nitrogen heterocycles involved in a wide range of industrial applications such as agrochemicals, corrosion inhibitors, dyes, optical brighteners, as well as biologically active agents. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Application of 4546-95-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics