Chen, Di-Ming et al. published their research in Journal of Solid State Chemistry in 2019 | CAS: 157069-48-2

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Among the nitrogen-containing heterocyclic compounds, triazoles emerge with superior pharmacological applications. 1,2,3-Triazoles are usually prepared following (3+2) cycloaddition protocols. A common technique for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However, the Huisgen strategy produces a mixture of isomers (typically 1,4- and 1,5-disubstituted) when used to produce substituted triazoles.Computed Properties of C9H7N3O2

A polyhedron-based metal-organic framework with a rare hexanuclear Co(II) cluster for selective sorption and chemical conversion for CO2 was written by Chen, Di-Ming;Zhang, Xue-Jing. And the article was included in Journal of Solid State Chemistry in 2019.Computed Properties of C9H7N3O2 This article mentions the following:

A new polyhedron-based metal-organic framework (MOF), namely {[Co6(OH)2(H2O)4(cpt)9](NO3)(DMF)13} (1, Hcpt = 4-(4′-carboxyphenyl)-1,2,4-triazole), was constructed by employment of a bifunctional triazolyl-carboxyl ligand Hcpt. Single crystal x-ray structural anal. shows that compound 1 features a rare hexanuclear {Co6(OH)2(H2O)6}10+ cluster and could be topol. viewed as a 10-connected bct net. Furthermore, compound 1 comprises octahedral cages with the inner diameter of 19.6 × 12.9 Å2 and 2D pore systems along the a and b axis with high d. of open metal centers generated by the removal of coordinated water mols., which contribute to a high CO2 adsorption capacity and significantly selective capture for CO2 over CH4 around room temperature In addition, the resulting activated 1a could behave as the heterogeneous Lewis catalyst facilitates the chem. fixation of CO2 coupling with epoxides into cyclic carbonates under mind conditions. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Computed Properties of C9H7N3O2).

4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Among the nitrogen-containing heterocyclic compounds, triazoles emerge with superior pharmacological applications. 1,2,3-Triazoles are usually prepared following (3+2) cycloaddition protocols. A common technique for unsubstituted triazoles is the Huisgen azide-alkyne 1,3-dipolar cycloaddition: a azide and an alkyne react at high temperature to form a ring. However, the Huisgen strategy produces a mixture of isomers (typically 1,4- and 1,5-disubstituted) when used to produce substituted triazoles.Computed Properties of C9H7N3O2

Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics