Chen, Dong published the artcileStudy of Six Green Insensitive High Energetic Coordination Polymers Based on Alkali/Alkali-Earth Metals and 4,5-Bis(tetrazol-5-yl)-2 H-1,2,3-triazole, Name: 1H-1,2,3-Triazole-4,5-dicarbonitrile, the publication is Chemistry – An Asian Journal (2017), 12(24), 3141-3149, database is CAplus and MEDLINE.
Constructing insensitive high-performance energetic coordination polymers (ECPs) with alkali/alkali-earth metal ions and a nitrogen-rich organic backbone has been proved to be a feasible strategy in this work. Six diverse dimensional novel ECPs were successfully synthesized from NaI, CsI, CaII, SrII, BaII ions and a nitrogen-rich triheterocyclic 4,5-bis(tetrazol-5-yl)-2 H-1,2,3-triazole (H3BTT). All compounds show outstanding stability and low sensitivity, the thermal stability of these ECPs are significantly improved as the structural reinforcement increases from 1D to 3D, in which the decomposition temperature of 3D BaII based compound is as high as 397°. Long-term storage experiments show that two of the compounds are stable enough at high temperature Moreover, the six compounds hold considerable detonation performances, in which CaII based compound possesses the detonation velocity of 9.12 km s-1, along with the detonation pressure of 34.51 GPa, exceeding those of most energetic coordination polymers. Burn tests further certify that the six compounds can be versatile pyrotechnics.
Chemistry – An Asian Journal published new progress about 53817-16-6. 53817-16-6 belongs to triazoles, auxiliary class Triazoles, name is 1H-1,2,3-Triazole-4,5-dicarbonitrile, and the molecular formula is C4HN5, Name: 1H-1,2,3-Triazole-4,5-dicarbonitrile.
Referemce:
https://en.wikipedia.org/wiki/1,2,3-Triazole,
Triazoles – an overview | ScienceDirect Topics