Chen, Xingkuan; Fang, Xinqiang; Chi, Yonggui Robin published an article in 2013, the title of the article was cis-Enals in N-heterocyclic carbene-catalyzed reactions: distinct stereoselectivity and reactivity.Product Details of 1469801-67-9 And the article contains the following content:
The first successful generation of cis-homoenolate equivalent from cis-enals under the catalysis of N-heterocyclic carbenes (NHCs) has been realized. The cis-homoenolate intermediates undergo effective reactions with α,β-unsaturated imines to afford chiral cyclic ketone products, e.g., I and II. Compared to the trans-enals, cis-enals show different stereoselectivities and new reactivity patterns. The experimental process involved the reaction of (R)-5-Benzyl-2-mesityl-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazol-2-ium tetrafluoroborate(cas: 1469801-67-9).Product Details of 1469801-67-9
The Article related to enal imine cyclization heterocyclic carbene, cyclic ketone stereoselective preparation, heterocyclic carbene stereoselective cyclization catalyst, Heterocyclic Compounds (One Hetero Atom): Ethylene Oxides and other aspects.Product Details of 1469801-67-9
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics