Let¡¯s face it, organic chemistry can seem difficult to learn, Recommanded Product: S-(Benzo[d]thiazol-2-yl)-N,N-dicyclohexylthiohydroxylamine, Especially from a beginner¡¯s point of view. Like 4979-32-2, Name is S-(Benzo[d]thiazol-2-yl)-N,N-dicyclohexylthiohydroxylamine, molecular formula is C8H10O2, belongs to isothiazole compound. In a document, author is Druzina, Anna A., introducing its new discovery.
Synthesis and Structure of Nido-Carboranyl Azide and Its Click Reactions
Novel zwitter-ionic nido-carboranyl azide 9-N-3(CH2)(3)Me2N-nido-7,8-C2B9H11 was prepared by the reaction of 9-Cl(CH2)(3)Me2N-nido-7,8-C2B9H11 with NaN3. The solid-state molecular structure of nido-carboranyl azide was determined by single-crystal X-ray diffraction. 9-N-3(CH2)(3)Me2N-nido-7,8-C2B9H11 was used for the copper(I)-catalyzed azide-alkyne cycloaddition with phenylacetylene, alkynyl-3 beta-cholesterol and cobalt/iron bis(dicarbollide) terminal alkynes to form the target 1,2,3-triazoles. The nido-carborane-cholesterol conjugate 9-3 beta-Chol-O(CH2)C-CH-N-3(CH2)(3)Me2N-nido-7,8-C2B9H11 with charge-compensated group in a linker can be used as a precursor for preparation of liposomes for Boron Neutron Capture Therapy (BNCT). A series of novel zwitter-ionic boron-enriched cluster compounds bearing a 1,2,3-triazol-metallacarborane-carborane conjugated system was synthesized. Prepared conjugates contain a large amount of boron atom in the biomolecule and potentially can be used for BNCT.
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