Extracurricular laboratory: Synthetic route of 135242-93-2

The synthetic route of 135242-93-2 has been constantly updated, and we look forward to future research findings.

Related Products of 135242-93-2,Some common heterocyclic compound, 135242-93-2, name is (1-Methyl-1H-[1,2,4]triazol-3-yl)methanol, molecular formula is C4H7N3O, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.

To a solution of 0.5 g (4.42 mmol, 1.0 eq.) of (l-methyl-li/-l,2,4-triazol-3-yl)methanol (Xlla) in 20 mL of acetonitrile was added 1.07 g (6.63 mmol, 1.5 eq.) of I,G -carbonyl and the mixture was stirred at room temperature for 2 h. Volatiles were removed in vacuo and the residue was resuspend in 20 mL of water. The mixture was extracted with 3 x 50 mL of 5% methanol in methylene chloride. The combined organic extracts were washed with 50 mL of sat. sodium carbonate solution, followed by 50 mL of brine, dried (T^SCL), filtered and the solvent was removed in vacuo to provide 0.77 g of ( 1 -methyl- 1 H- 1 2.4-triazol-3-yl)methyl 1 //-imidazole- 1 -carboxy late (XIHa).

The synthetic route of 135242-93-2 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; ARBUTUS BIOPHARMA CORPORATION; KULTGEN, Steven; COLE, Andrew G.; (217 pag.)WO2020/23710; (2020); A1;,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics