Related Products of 1704-62-7, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 1704-62-7, Name is 2-(2-(Dimethylamino)ethoxy)ethanol, SMILES is CN(CCOCCO)C, belongs to Triazoles compound. In a article, author is Forder, Timothy N., introduce new discover of the category.
Post-synthetic ‘Click’ Synthesis of RAFT Polymers with Pendant Self-immolative Triazoles
Self-immolative linkers offer efficient mechanisms for deprotecting ‘caged’ functional groups in response to specific stimuli. Herein we describe a convenient ‘click’ chemistry method for introducing pendant self-immolative linkers to a polymer backbone through post-polymerization modification. The introduced triazole rings serve both to anchor the stimuli-cleavable trigger groups to the polymer backbone, while also forming a functional part of the self-immolation cascade. We investigate the polymerization kinetics, post-synthetic modification, and self-immolation mechanism of a model polymer system, and discuss avenues for future studies on poly-pendant self-immolative triazoles as a modular, stimuli-responsive macromolecule platform.
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