Hauptmann, Siegfried; Wilde, Horst published an article in 1976, the title of the article was Substituent effects on the polarographic reduction of 1-amino-4-aryl-1,2,3-triazoles and 1H-4-aryl-1,2,3-triazoles.Formula: C9H9N3 And the article contains the following content:
Cathodic half-wave potentials (E1/2) for I (R = NH2, H; X = p-F, p-Cl, p-Br, p-Me, etc.), determined in MeCN at 20°, were between -2.1 and -2.6 V. Linear relations were found between E1/2 and the π-electron d. at C(5), as well as Hammett σ values. Pos. ρ values indicate a nucleophilic mechanism. The experimental process involved the reaction of 4-(p-Tolyl)-1H-1,2,3-triazole(cas: 5301-96-2).Formula: C9H9N3
The Article related to reduction electrochem triazole mechanism, reaction constant electrochem reduction, Physical Organic Chemistry: Oxidation-Reduction Reactions (Including Hydrogenation) and other aspects.Formula: C9H9N3
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics