Hu, Linyu; Dai, Chunlong; Chen, Liwei; Zhu, Yuhao; Hao, Yuchen; Zhang, Qinghua; Gu, Lin; Feng, Xiao; Yuan, Shuai; Wang, Lu; Wang, Bo published an article in 2021. The article was titled 《Metal-Triazolate-Framework-Derived FeN4Cl1 Single-Atom Catalysts with Hierarchical Porosity for the Oxygen Reduction Reaction》, and you may find the article in Angewandte Chemie, International Edition.Application of 288-36-8 The information in the text is summarized as follows:
The construction of single-atom catalysts (SACs) with high single atom densities, favorable electronic structures and fast mass transfer is highly desired. We have utilized metal-triazolate (MET) frameworks, a subclass of metal-organic frameworks (MOFs) with high N content, as precursors since they can enhance the d. and regulate the electronic structure of single-atom sites, as well as generate abundant mesopores simultaneously. Fe single atoms dispersed in a hierarchically porous N-doped carbon matrix with high metal content (2.78 wt %) and a FeN4Cl1 configuration (FeN4Cl1/NC), as well as mesopores with a pore:volume ratio of 0.92, were obtained via the pyrolysis of a Zn/Fe-bimetallic MET modified with 4,5-dichloroimidazole. FeN4Cl1/NC exhibits excellent oxygen reduction reaction (ORR) activity in both alk. and acidic electrolytes. D. functional theory calculations confirm that Cl can optimize the adsorption free energy of Fe sites to *OH, thereby promoting the ORR process. The catalyst demonstrates great potential in zinc-air batteries. This strategy selects, designs, and adjusts MOFs as precursors for high-performance SACs. In the part of experimental materials, we found many familiar compounds, such as 1H-1,2,3-Triazole(cas: 288-36-8Application of 288-36-8)
1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Application of 288-36-8
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics