Katritzky, Alan R.; Xie, Linghong published the artcile< para-Formylation of nitroarenes via vicarious nucleophilic substitution of hydrogen with tris(benzotriazol-1-yl)methane>, Name: Tris(1H-benzo[d][1,2,3]triazol-1-yl)methane, the main research area is formylation nitroarene nucleophilic substitution; benzotriazolylmethane nitroarene formylation; nitroarylaldehyde preparation.
Reaction of nitrobenzenes RC6H4NO2 (R = H, 2-Ph, 2-NO2, 2-Br, 3-F, 2-Cl) and 1-nitronaphthalene with tris(benzotriazol-1-yl)methyl anion [Bt3C-; Bt = benzotriazol-1-yl] afforded 4-bis(benzotriazol-1-yl)methylated products R-4-(Bt2CH)C6H3NO2, which, upon treatment with ZnBr2 and aqueous HCl, yielded the corresponding 4-nitroarylaldehydes R-4-(CHO)C6H3NO2 in 41-86% yield.
Tetrahedron Letters published new progress about Aromatic nitro compounds Role: RCT (Reactant), RACT (Reactant or Reagent). 88088-95-3 belongs to class triazoles, and the molecular formula is C19H13N9, Name: Tris(1H-benzo[d][1,2,3]triazol-1-yl)methane.
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics