《Spin crossover in iron(II) Hofmann clathrates analogues with 1,2,3-triazole》 was written by Kuzevanova, Iryna S.; Kucheriv, Olesia I.; Hiiuk, Volodymyr M.; Naumova, Dina D.; Shova, Sergiu; Shylin, Sergii I.; Kotsyubynsky, Volodymyr O.; Rotaru, Aurelian; Fritsky, Igor O.; Gural’skiy, Il’ya A.. HPLC of Formula: 288-36-8This research focused ontriazolyl iron palladium platinum cyanometallate preparation crystal mol structure; spin crossover iron Hofmann clathrate analog triazolyl iron clathrate. The article conveys some information:
Hofmann-like cyanometallic complexes represent one of the biggest and well-known classes of FeII spin-crossover compounds In this paper, authors report on the first FeII Hofmann clathrate analogs with unsubstituted 1,2,3-triazole, which exhibit temperature induced spin transition. Two new coordination polymers with the general formula [FeII(1,2,3-triazole)2MII(CN)4] (M = Pt, Pd) undergo abrupt hysteretic spin crossover in the range of 190-225 K as revealed by magnetic susceptibility measurements. Two compounds are isostructural and are built of infinite cyanometallic layers which are supported by 1,2,3-triazole ligands. The thermal hysteresis loop is very stable at different scan rates from 0.5 to 10 K min-1. The compounds display strong thermochromic effect, changing their color from pink in the low-spin state to white in the high-spin state. Their findings show that 1,2,3-triazole is suitable for elaboration of spin-crossover Hofmann clathrate analogs, and its use instead of more classical azines can advantageously expand this family of complexes. In the part of experimental materials, we found many familiar compounds, such as 1H-1,2,3-Triazole(cas: 288-36-8HPLC of Formula: 288-36-8)
1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties HPLC of Formula: 288-36-8
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics