Lai, Qi published the artcile1,2,3-Triazole with linear and branched catenated nitrogen chains – The role of regiochemistry in energetic materials, HPLC of Formula: 84406-63-3, the publication is Chemical Engineering Journal (Amsterdam, Netherlands) (2021), 128148, database is CAplus.
Two energetic mols. possessing a linear and branched N8 structure were synthesized based on the oxidative coupling of N-aminotriazoles. Despite the same chem. formula and azo functionality, the decomposition temperatures (Td) of these two regioisomers reflect a gap of more than 80°C. Based on the data of single crystal X-ray diffraction, comparative investigation associated with the bond length and stacking pattern rationalize the different properties of d. and mol. stability. Theor. analyses, e.g., charge distribution and Hirshfeld surface, were carried out subsequently to gain more insight into the regiochem. of catenated nitrogen-atom chains. The difference of charge distribution between two mols. caused by regional heterogeneity is the main reason for their different stabilities.
Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about 84406-63-3. 84406-63-3 belongs to triazoles, auxiliary class Triazole,Nitro Compound, name is 4-Nitro-2H-1,2,3-triazole, and the molecular formula is C2H2N4O2, HPLC of Formula: 84406-63-3.
Referemce:
https://en.wikipedia.org/wiki/1,2,3-Triazole,
Triazoles – an overview | ScienceDirect Topics