Li, Mingyue; Fu, Yaomei; You, Siqi; Yang, Yu; Qin, Chao; Zhao, Liang; Su, Zhongmin published an article in 2021. The article was titled 《Hexanuclear nickel-based [P4Mo11O50] with photocatalytic reduction of CO2 activity》, and you may find the article in Inorganic Chemistry Communications.Related Products of 288-36-8 The information in the text is summarized as follows:
A new polyoxometalate based organic-inorganic hybrid [Ni6(trz)2(Htrz)13][H4P4Mo11O50]·7H2O (1), constructed from a hexanuclear [Ni6(trz)2(Htrz)13] building block and a new polyoxometalate [H4P4Mo11O50] cluster, was synthesized under a hydrothermal condition. In this 3D structure, each [Ni6(trz)2(Htrz)13] secondary building unit (SBU) connects with four neighbored [Ni6(trz)2(Htrz)13] and four [H4P4Mo11O50] clusters, forming an eight-connected node. While each [H4P4Mo11O50] cluster bridges four [Ni6(trz)2(Htrz)13] SBUs as a four-connected node. So the 3D framework of 1 can be simplified to a binodal (4,8)-connected gsp2 topol. with point symbol [44·62][416·612]. The photocatalytic reduction of CO2 under visible light reveals that the highest yield of CO was 689.86μmol g-1 when 1 is used as catalyst, Ru(bpy)3Cl2 as a photosensitizer and TEOA as a sacrificial agent. The mechanism of the photoreduction of CO2 is confirmed by Mott-Schottky, photocurrent, and fluorescence quenching experiments This research provides a new strategy for the design of cheap and efficient POM-based photocatalysts. The results came from multiple reactions, including the reaction of 1H-1,2,3-Triazole(cas: 288-36-8Related Products of 288-36-8)
1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Related Products of 288-36-8
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics