Electric Literature of 1455-77-2, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 1455-77-2 name is 3,5-Diamino-1,2,4-triazole, This compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.
The reaction mixture for the synthesis of new class II hybridfluorinated is formed by two metal cations in fluorinated forms FeF2and FeF3, an aqueous solution of hydrofluoric acid 4percent (prepared from40percent HF, Riede-deHaen), a solvent such as ethanol, which is polar andprotic, and with a cyclic organic molecule (3,5-diamino-1,2,4-triazole).The solvent volume was fixed to 10 mL with a constant concentration[FeII] + [FeIII] = 0.15 mol L?1 and an equimolar ratio n(FeII)/n(FeIII)= 1. Indeed, [Fe3F8(H2O)2](Am2TAZ)2 is obtained from a mixture of85 mg of FeF3 (0.75 mmol), 70 mg of FeF2 (0.75 mmol), 2.52 mL of HF2.3M (5.8 mmol) and 57 mg (Am2TAZ) (0.57 mmol).The starting materials were placed in a reactor when filling 50percent ofthe autoclave. After manipulation, the solid product is washed with thesolvent used, then air dried at room temperature. As a result, a newmixed hybrid fluoride was obtained. Therefore, the exploration of thissystem FeF2/ FeF3 – HF – (Am2TAZ) ? EtOH, led by hydrothermalsynthesis at 120 ¡ãC for 72 h, yielded to the elaboration of a new phaseof formula [Fe3F8(H2O)2](Am2TAZ)2 colorless with prismatic shape.
At the same time, in my other blogs, there are other synthetic methods of this type of compound, 3,5-Diamino-1,2,4-triazole, and friends who are interested can also refer to it.
Reference:
Article; Bouketaya, Sabrine; Smida, Mouna; Abdelbaky, Mohammed S.M.; Dammak, Mohamed; Garcia-Granda, Santiago; Journal of Solid State Chemistry; vol. 262; (2018); p. 343 – 350;,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics