Research speed reading in 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. 288-36-8, name is 1H-1,2,3-Triazole belongs to triazoles compound, it is a common compound, a new synthetic route is introduced below. 288-36-8
Compound 1a was prepared by adapting a procedure described. 8 A mixture of Cu2O (0.12 g, 0.80 mmol), 1,2,3-triazole (0.48 mL, 8.0 mmol), 1,10-phenanthroline (0.29 g, 1.6 mmol), iodobenzene (1.1 mL, 9.6 mmol) and tetramethylammonium fluoride (2.2 g, 24 mmol) was heated under argon at 120 C for 48 h. CH2Cl2 (10 mL) was added to the residue. After filtration over celite, the organic phase was washed with brine (2 * 5 mL) and the solvent was evaporated. The crude product was purified by chromatography over silica gel (eluent: CH2Cl2/heptane 1:1 to CH2Cl2/AcOEt 1:1) to afford the pure compound in 47% yield as an orange powder: mp 58 C; 1H NMR (CDCl3, 300 MHz) 7.42-7.49 (m, 1H), 7.51-7.58 (m, 2H), 7.74-7.78 (m, 2H), 7.88 (br s, 1H), 8.03 (d, 1H, J = 0.9 Hz). The 1H NMR data are in accordance with those previously described. 27 13C NMR (CDCl3, 75 MHz) 120.8 (2CH), 121.9 (CH), 129.0 (CH), 129.9 (2CH), 134.6 (CH), 137.2 (C).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 288-36-8, and we look forward to future research findings.
Reference:
Article; Nagaradja, Elisabeth; Bentabed-Ababsa, Ghenia; Scalabrini, Mathieu; Chevallier, Floris; Philippot, Stephanie; Fontanay, Stephane; Duval, Raphael E.; Halauko, Yury S.; Ivashkevich, Oleg A.; Matulis, Vadim E.; Roisnel, Thierry; Mongin, Florence; Bioorganic and Medicinal Chemistry; vol. 23; 19; (2015); p. 6355 – 6363;,
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics