Design, structure and luminescent properties of a novel two-dimensional Cd(II) coordination polymer constructed from in situ generated 1-methyl-2-(3H-[1-3]triazol-4-yl)-1H-benzoimidazole was written by Sun, Feng;Yin, Zheng;Sun, Chen-Guang;Kurmoo, Mohamedally;Zeng, Ming-Hua. And the article was included in Inorganic Chemistry Communications in 2014.Product Details of 4546-95-6 This article mentions the following:
A cadmium(II) coordination polymer, namely {[Cd5(Ln)6Cl4]·2H2O}n (1, HLn = 1-methyl-2-(3H-[1-3]triazol-4-yl)-1H-benzoimidazole), was constructed from in situ generated HLn under hydrothermal condition. The unsuccessful synthesis of 1 under similar synthesis condition using HLn as reactant suggests the in situ reaction is crucial for the assembly of the compound Crystallog. study reveals that 1 processes layer structure in which chains of [Cd3(Ln)4Cl4]2 – were connected by a pair of Cd ions. These layers further stack in an AAA model to form a 3D supramol. framework and hydrogen bonding as well as π-π interaction were formed between adjacent layers to stabilize the framework. TGA indicates that 1 is highly thermally stable up to ∼380°. The luminescence of 1 in the solid state which may be assigned to intraligand transition shows a blue shift of 16 nm compared to that of HLn·HCl. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Product Details of 4546-95-6).
1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. However, triazoles are also useful in bioorthogonal chemistry, because the large number of nitrogen atoms causes triazoles to react similar to azides. Triazoles are compounds with a vast spectrum of applications, varying from materials (polymers), agricultural chemicals, pharmaceuticals, photoactive chemicals and dyes.Product Details of 4546-95-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics