Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN1]nickel(II) decahydrate was written by Sun, Weixuan;Yu, Yaqin;Wang, Guanjun;Wu, Xiaohui. And the article was included in Acta Crystallographica, Section E: Structure Reports Online in 2012.Synthetic Route of C9H7N3O2 This article mentions the following:
In the title compound, [Ni(C9H6N3O2)2(H2O)4]·10H2O, the NiII ion lies on a 2-fold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four H2O mols., two of which also lie on the 2-fold rotation axis. In the crystal, the complex mols. and uncoordinated H2O mols. are linked via intermol. O-H···N and O-H···O H bonds, forming a three-dimensional supramol. network. π-π Interactions between the benzene rings provide addnl. stability of the crystal packing [centroid-centroid distance = 3.792(2) Å]. Crystallog. data and at. coordinates are given. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Synthetic Route of C9H7N3O2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. Triazoles are important five-member nitrogen heterocycles involved in a wide range of industrial applications such as agrochemicals, corrosion inhibitors, dyes, optical brighteners, as well as biologically active agents. Triazoles are compounds with a vast spectrum of applications, varying from materials (polymers), agricultural chemicals, pharmaceuticals, photoactive chemicals and dyes.Synthetic Route of C9H7N3O2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics