Edge-directed assembly of a 3D 2p-3d heterometallic metal-organic framework based on a cubic Co8(TzDC)12 cage was written by Tian, Dan;Liu, Sui-Jun;Chang, Ze;Zhang, Ying-Hui;Zhao, Jiong-Peng;Bu, Xian-He. And the article was included in CrystEngComm in 2013.Product Details of 4546-95-6 This article mentions the following:
A three-dimensional (3D) heterometallic metal-organic framework containing cubic-like cages, {[Co3Na6(TzDC)4(H2O)6]·7H2O}n (1) (H3TzDC = 1,2,3-triazole-4,5-dicarboxylic acid), was synthesized by the edge-directed self-assembly of TzDC3-, Co2+ and Na+ ions. Crystal data reveals that one hydrous Co2+ cation is embedded in the central cavity of a cubic-like cage [Co8(TzDC)12]20- with eight Co2+ cations as the corners and twelve TzDC3- ligands as the edges. The cages are further bridged by Na+ ions to result in a 3-dimensional framework with pcu topol. Magnetic study indicates that besides the spin-orbit coupling of Co2+ ions, an antiferromagnetic exchange interaction was found to exist between the Co2+ ions in the Co9 cluster of 1. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6Product Details of 4546-95-6).
1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. However, triazoles are also useful in bioorthogonal chemistry, because the large number of nitrogen atoms causes triazoles to react similar to azides. Triazoles are compounds with a vast spectrum of applications, varying from materials (polymers), agricultural chemicals, pharmaceuticals, photoactive chemicals and dyes.Product Details of 4546-95-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics