A 3D-diamond-like metal-organic framework: Crystal structure, nonlinear optical effect and high thermal stability was written by Wang, Lihua;Ye, Yingxiang;Zhang, Liuqin;Chen, Qianhuo;Ma, Xiuling;Zhang, Zhangjing;Xiang, Shengchang. And the article was included in Inorganic Chemistry Communications in 2015.Recommanded Product: 157069-48-2 This article mentions the following:
A new metal-organic framework [Zn(cpt)(ATZ)]n (1, HATZ = 5-amino-1H-tetrazol, Hcpt = 4-(4H-1,2,4-Triazol-4-yl)benzoic acid), has been solvothermally synthesized and structurally characterized by single crystal X-ray diffraction. Structural anal. shows that compound 1 is a three-dimensional (3D) framework with 3-fold interpenetrated diamond topol. where the Zn(II) centers are all 4-coordinated. Compound 1 exhibits high thermal stability up to 370 °C, and weak second-order nonlinear optical coefficient as ca. 0.13 times as that of potassium dihydrogen phosphate (KDP), and also displays blue photoluminescence at room temperature In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Recommanded Product: 157069-48-2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The triazole ring is a relatively stable functional group, and the triazole bond can be used for a variety of applications, such as replacing the phosphate backbone of DNA. Due to the structural characteristics, both 1,2,3- and 1,2,4-triazoles are able to accommodate a broad range of substituents (electrophiles and nucleophiles) around the core structures and pave the way for the construction of diverse novel bioactive molecules.Recommanded Product: 157069-48-2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics