Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Product Details of 464-48-2464-48-2, Name is (-)-Camphor, SMILES is O=C1[C@@](C2(C)C)(C)CC[C@@]2([H])C1, belongs to Triazoles compound. In a article, author is Han, Haitao, introduce new discover of the category.
4.8 nm Concave {M-72} (M=Co, Ni, Fe) metal-organic polyhedra capped by 18 calixarenes
Three 4.8 nm isostructural {M-72} (M=Co-II for CIAC-128, Ni-II for CIAC-129, Fe-II for CIAC-130) metal-organic polyhedra (MOPs) are constructed by eighteen M-4-p-tert-butylthiacalix[4]arene (M-4-TC4A) units bridged via sixteen four-connected 5,5 ‘-(1H-1,2,4-triazole-3,5-diyl) diisophthalic acid (H(4)TADIPA) linkers. These MOPs are featured with a rarely reported concave coordination cage, which can be simplified as a squeezed double-decker hexagonal prism pressed from the top and bottom hexagonal faces. Furthermore, CIAC-128, CIAC-129 and CIAC-130 are the highest nuclearity discrete clusters of Co, Ni and Fe reported so far. CIAC-128 has higher separation selectivity of C3H8 than CH4 under ambient conditions, and also exhibits separation selectivity for C2H6/CH4, C2H2/CH4, and C2H4/CH4. In addition, CIAC-128 can provide the cavity for the confined synthesis of noble metal nanoclusters such as Pd nanoclusters and the resulting Pd@CIAC-128 hybrids show higher electrocatalytic activity than commercial Pt/C towards hydrogen evolution reaction (HER).
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 464-48-2. Product Details of 464-48-2.