Category: triazolesIn 2020 ,《Graphite-like polyoxometalate-based metal-organic framework as an efficient anode for lithium ion batteries》 appeared in CrystEngComm. The author of the article were Yang, Xiya; Zhu, Peipei; Ma, Xiaoliang; Li, Wenjing; Tan, Zenglong; Sha, Jingquan. The article conveys some information:
A new polyoxometalate (POM) pillared metal-organic framework (POMOF), [Cu24(Trz)16(H2O)Cl4(HPMo12O40)] (Cu-POM, Trz = 1,2,3-triazole), was synthesized and characterized. Crystal anal. reveals that the Keggin POMs are inserted into copper-triazole layers with a graphite-like structure generating a POM-supported porous three-dimensional framework. Owing to the combination of the multi-electron redox property of POM units and the open porous framework, Cu-POM can be utilized as an anode material for lithium ion batteries (LIBs), and exhibits a reversible capacity of 525 mA h g-1 at a c.d. of 100 mA g-1 after 100 cycles. Moreover, to illustrate lithium storage, the impedance spectra of compound Cu-POM during the first and 100th charge process have also been studied. The study of Cu-POM in this work might guide the development of POM-based electrode materials for LIBs. The experimental part of the paper was very detailed, including the reaction process of 1H-1,2,3-Triazole(cas: 288-36-8Category: triazoles)
1H-1,2,3-Triazole(cas: 288-36-8) belongs to triazoles. Triazoles are an important group of nitrogen-containing five-membered heterocyclic scaffolds. Triazoles are core structures of several drugs and pharmaceutical agents. Triazole derivatives possess antimicrobial, antiparasitic, antidiabetic, analgesic, and anti-inflammatory properties Category: triazoles
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics