Two threefold Interpenetrating 3D Supramolecular Networks Based on 1D Chains and Hydrogen-bond Interactions was written by Zhu, Ai-Xin;Yang, Li-Bo;Fang, Xiao-Dan;Zhang, Ce;Dou, Ai-Na;Yin, Qi. And the article was included in Zeitschrift fuer Anorganische und Allgemeine Chemie in 2017.Synthetic Route of C9H7N3O2 This article mentions the following:
The coordination compounds, [Cu2(Htba)(tba)Cl] (1) and [Ag2(Htba)(tba)(NO3)] (2), were synthesized under solvothermal conditions by using a triazolate-carboxylate bifunctional organic ligand 4-(4H-1,2,4-triazol-4-yl)benzoic acid (Htba). X-ray single crystal diffraction analyses for the two complexes revealed that compounds 1 and 2 exhibit one-dimensional (1D) chain structures with uncoordinated carboxylic groups, which are further connected by O-H璺矾璺疧 hydrogen bonds into 3D, threefold interpenetrating supramol. frameworks with different topologies belonging to 4-connected and (2,4)-connected nets with the (42璺?2璺?02)(43璺?2璺?)2(44璺?2) and (125璺?6)(12)2 Schlaefli symbols, resp. The photoluminescent measurements reveal that both 1 and 2 exhibit bluish-purple emissions in the solid state at room temperature In addition, the compound 2 can serve as an antenna for sensitizing the visible-emitting of the lanthanide cations to display their characteristic emissions. In the experiment, the researchers used many compounds, for example, 4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2Synthetic Route of C9H7N3O2).
4-(4H-1,2,4-Triazol-4-yl)benzoic acid (cas: 157069-48-2) belongs to triazole derivatives. The many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. Many triazoles have antifungal effects: the triazole antifungal drugs include fluconazole, isavuconazole, itraconazole, voriconazole, pramiconazole, ravuconazole, and posaconazole and triazole plant-protection fungicides include epoxiconazole, triadimenol, myclobutanil, propiconazole, prothioconazole, metconazole, cyproconazole, tebuconazole, flusilazole and paclobutrazol.Synthetic Route of C9H7N3O2
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics