A hexanuclear CoII complex assembled with 1H-1,2,3-triazole-4,5-dicarboxylic acid: synthesis, crystal structure and magnetic property was written by Zou, Ji-yong;Shi, Wei;Gao, Hong-ling;Cui, Jian-zhong;Cheng, Peng. And the article was included in Wuji Huaxue Xuebao in 2014.SDS of cas: 4546-95-6 This article mentions the following:
A new hexanuclear CoII complex, namely [Co6(TDA)4(H2O)14]·5H2O (1) (H3TDA = 1H-1,2,3-triazole-4,5-dicarboxylic acid), has been successfully synthesized and characterized by IR spectra, elemental anal., thermogravimetric anal., powder and single-crystal X-ray diffraction. Complex 1 crystallizes in orthorhombic space group P21212, with cell parameters: a = 1.64730(2) nm, 6 = 1.65330(2) nm, c = 0.7326 90(10) nm and Flack parameter of 0.00(13). In title complex, six CoII ions are connected by four TDA3- ligands to form a hexanuclear CoII unit, which can be extended to a 3D supramol. architecture through the hydrogen-bonding interactions. Magnetic study reveals the dominant antiferromagnetic interaction exist between CoII ions in 1. In the experiment, the researchers used many compounds, for example, 1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6SDS of cas: 4546-95-6).
1H-1,2,3-Triazole-4,5-dicarboxylic acid (cas: 4546-95-6) belongs to triazole derivatives. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. Due to the structural characteristics, both 1,2,3- and 1,2,4-triazoles are able to accommodate a broad range of substituents (electrophiles and nucleophiles) around the core structures and pave the way for the construction of diverse novel bioactive molecules.SDS of cas: 4546-95-6
Referemce:
1,2,3-Triazole – Wikipedia,
Triazoles – an overview | ScienceDirect Topics